2022一2023学年度10月1切5高三化学试题I:127可能用到的相对原子质量：H:10:16C:12N:14S:32Cu:64K:39一、选择题（共21题，年小题只有一个选项符合题毫意，每小题2分，共42分）1.化学与环境、材料密切相关，下列说法错误的是八NoA./汽车尾气中的NO、C0都是汽油燃孵的产塑1B/氮氧化物是光化学烟雾的主要污染物C.生石灰能爱益，4驿煤脑的股破剂D.相合金大量用于高铁建设2.化学与生活密切相关，下列叙述正确的是H00.H以®4.漂白粉与盐酸可混合使用以提高消毒效果B.温室气体是形成酸雨的主要物质C.棉花、麻和蚕丝均为碳水化合物铷D男赛台注天雾3.下列离子方程式书写正确的是CaloH+Nazcos=Lacos vNaorA.石灰乳号Na,C0,溶液混合：℃a4C06aC0,↓将大星招H6四，B.Fcth04三f飞S04十h个C.Fe与稀疏酸反检的离子方程式：2e+6H-2Fe3++3H,↑LalHioshf NaoH:二D.Ca(HC03)2溶液与少量NaOH溶液反应：HC0;+Ca2+0H-CaCo,↓+H,04.下列各组离子在给定条件下一定能大量共存的是A.无色透明的溶液：Na、K、NH、MOB.常温下pH小于7的溶液：N、Fe24、Br、co2C.遇酞变红的溶液：Ba2+、K、NO;、CfD.含氯化铁的K、Ba2+、NO3、OH5.下列物质在给定条件下能一步实现的是Fe,04A.Pe..rcB.NaCl(a、eo8→NaHC0,sNa,C0,加热c.Ca(oH),co→CaCo,ChlooroCH,COOHD.Cu-A→Cu0→Cu(OH),第1页

14.C【解析】材料强调建立与消费者的直接联系，基于库存和销售数据及时调整产能计划，优化产品营销，提升服务体验，这说明数字化转型有利于企业精准对接市场，促进产品销售，也有利于企业提升服务水，优化客户体验，②③正确。材料涉及的是企业的数字化转型，是经营模式的调整，并不涉及“改进制造工艺，降低生产成本”，①排除。该企业的数字化转型并不能增加产品价值，④不选。故本题选C。15.B16.A【解析】强化反垄断，深入推进公竞争政策实施，营造公竞争的市场环境为各类市场主体创造广阔的发展空间，促进各类主体公竞争，实现共同富裕，故A符合题意。题干问的是对助力共同富裕的意义，强调公。而通过推进公竞争政策实施提高企业运营效率，侧重效率，故B不符合题意。C与助力共同富裕无关，同时从长远来看，台经济趋于垄断会降低台影响力，降低规模效益，故不选。题干问的是对共同富裕的意义，D强调的是宏观调控与市场的关系，不符合题意。故本题选A。二、非选择题（共52分）17.①中国共产党的初心和使命是为中国人民谋幸福，为中华民族谋复兴，中国共产党带领人民有效应对新冠疫情等重大挑战，为社会主义现代化建设和中华民族谋复兴创造良好的社会环境。(4分)②坚持和完善具有强大生命力和巨大优越性的中国特色社会主义制度，有利于通过制度优势确保清零政策能够落地并发挥效果，保障人民幸福安康。(4分)③坚持中国特色社会主义思想以人为本、人民至上的价值取向，依靠人民战胜疫情，护佑人民康宁。(4分)18.①个体私营经济是社会主义市场经济的重要组成部分。(4分)②改革开放以来，湖南个体私营经济不断发展壮大，成为稳定经济增长和改善民生的重要力量、创业就业的主要领域、技术创新的重要主体、国家税收的重要来源，为湖南社会主义市场经济发展、政府职能转变、农村富余劳动力转移、国际市场开拓等发挥了重要作用。(8分)19.①充分发挥市场作用，更好发挥政府作用，推动有效市场和有为政府更好结合。②提高每吨水的价格，运用价格杠杆调节水资源配置。③由当地政府出面干预，分配水库库存量到不同村民小组和农户家庭，实现科学的宏观调控。④由当地村民选出德高望重的长者，各村民小组各派一位代表，协商讨论出一个满意的方案。（每点4分，任答三点即可，其他方法，言之有理即可得分)20.(1)①中国特色社会主义思想植根于坚持和发展中国特色社会主义新的伟大实践，是时代的产物，是党和人民实践经验和集体智慧的结晶。(2分)②中国特色社会主义思想是当代中国马克思主义、二十一世纪马克思主义，是中华文化和中国精神的时代精华，实现了马克思主义中国化新的飞跃。(2分)坚持和发展中国特色社会主义思想，有利于坚持和发展马克思主义、坚持和发展科学社会主义。(2分)③坚持中国特色社会主义思想，有利于激励全体中华儿女不断奋进，夺取新时代中国特色社会主义伟大胜利、实现中华民族伟大复兴；有利于推动构建新型国际关系和人类命运共同体，为世界和与发展作出重大贡献；有利于不断推进党的自我革命，提高中国共产党与时俱进的执政能力。（三个“有利于”，任答其中两个“有利于”，就可得4分)(2)①新时代中国青年要树立远大理想：树立对马克思主义的信仰、对中国特色社会主义的信念、对中华民族伟大复兴中国梦的信心。②新时代中国青年要练就过硬本领：努力掌握科学文化知识和专业技能，在学中增长知识、锤炼品格，在工作中增长才干、练就本领，在修养中锤炼品德修为，自觉树立和践行社会主义核心价值观。③新时代中国青年要勇于砥砺奋斗：要勇做走在时代前列的奋进者、开拓者、奉献者，担负时代使命，在担当中历练，在尽责中成长，让青春在新时代改革开放的广阔天地中绽放，让人生在实现中国梦的奋进追逐中展现出勇敢奔跑的英姿，努力成为德智体美劳全面发展的社会主义建设者和接班人！（可以从青年人“有理想、有本领、有担当”的角度展开，共6分)思想政治参考答案一2

要生用人打名师导学·选择性考试第一轮总复·生物(3)兴奋在突触处传递比在神经纤维上的选项实验操作预期结果传递速度要慢。原因是兴奋由突触前膜传至剪断背根中央处，刺激背根向中段蛙后突触后膜，需要经历化学信号转换，如递质的分别电刺激背根向肢收缩；刺激背根外周释放、扩散以及对突触后膜作用的过程。中段、外周段段不发生反应【易错提醒】剪断腹根中央处，刺激腹根向中段蛙后(1)静息电位不等于零电位B分别电刺激腹根向肢收缩；刺激腹根外周静息电位时，由于K+外流，使得膜外的阳中段、外周段段不发生反应离子浓度多于阴离子浓度，而膜内的阴离子浓剪断脊神经，分别蛙后肢均不收缩度多于阳离子，表现为外正内负，不是零电位。电刺激背根、腹根(2)神经纤维上兴奋的传导方向：在体内剪断背根、腹根中央蛙后肢收缩与离体情况不同处，电刺激脊神经①离体时，刺激神经纤维上某处，兴奋可【重点归纳】判断反射弧中受损部位的沿神经纤维双向传导。方法②在生物体内，神经纤维上的兴奋只能来(1)判断传出神经是否受损：将电流计连自感受器，并沿反射弧单向传导至效应器，所接在神经纤维上，当神经纤维受到刺激时，若以在生物体内，兴奋在神经纤维上是单向传电流计不发生偏转说明受损部位是神经纤维；导的。若电流计发生偏转说明受损的部位可能是骨例3将青蛙脑破坏保留脊髓，在脊柱下骼肌或突触。部打开脊椎骨，剥离出脊髓一侧的一对脊神经(2)判断骨骼肌是否受损：刺激骨骼肌，若根（包含背根、腹根和由背根腹根合并成的脊骨骼肌不收缩，说明受损的部位是骨骼肌神经，见下图)。已知分别电刺激背根、腹根、(3)判断突触是否受损：刺激骨骼肌，若骨脊神经均可引起蛙同侧后肢发生收缩。若利骼肌收缩，说明骨骼肌正常；然后刺激神经，若用上述实验材料设计实验，以验证背根具有传电流计偏转，但骨骼肌不收缩，则说明受损的入功能，腹根具有传出功能，实验操作和预期部位是突触。结果都正确的一组是背根脊神经脊髓腹根246

组别①②①DNA分子，可能引起,攻击使其活性下降引起细胞衰老葡萄糖溶液面萄糖溶液+葡萄糖溶液十葡萄糖溶液(2)乳酸萄糖溶液(填“能”或“不能”)作为神经元的能源物质，原因是实验处理无蓝水酵母菌酵母汁A溶液B溶液_。抑制MCT可降低神经元损伤，依据是实验结果+(3)某兴趣小组发现，人体运动强度与O,的消耗量和血液中乳酸含量也有密切关系（如图2）。注“+”表示有乙醇生成，“-”表示无乙醇生成A级冲液提供酶促反应的适宜pH,以确保酶的活性①人体无氧呼吸时葡萄糖中的能量去向有②在三种不同的运动强度下，请判断肌肉细胞中C0,的产生量与O,的消耗量的关系，并B可选用溴麝香草酚蓝水溶液检测有无乙醇的生成说明理由C.第⑥组的实验处理为葡萄糖溶液+A溶液+B溶液D.①②③组对比可验证利用无细胞的醇母汁可以进行乙醇发酵12.(14分)某学小组用相关装置测定酵母菌细胞呼吸的方式，相关数据测定结果如图所示。请回答下列问题10.某实验小组欲利用核桃幼苗研究氮素形态对根系呼吸速率的影响，在其他条件相同且适宜的(1)在200~300s时间段内，酵母菌的细胞呼吸方式为百精含量/(mgL)情况下，通过调整营养液中NH-N与NO-N的比例，共设置A(100%:0%)、B(75%,此时间段最终产生的物质除酒精25%)、C(50%:50%)、D(25%:75%)、E(0%:100%)5个氮素形态，连续每月测定并统计外，还有一02含量一次。进行素形态处理前对栽培基质浇灌大量清水，最后测定实验结果如图所示。下列(2)在0~100s时间段内，装置中酵母菌(填“能”或酒精含量/52述正确的是“不能”)发生[H与O2结合生成水，判断依据是4。30s后，醇母菌细胞呼吸产生的C0,与酒精的物资的量0350时间(填“相等”或“不相等”)，原因是3)将酵母菌置于含有葡萄糖溶液的密闭的锥形瓶中，测得C0的释放量比O的吸收量大1A根细胞进行无氧呼吸消耗水的场所是细胞质基质倍，则有氧呼吸消耗的葡萄糖的量与无氧呼吸消耗的葡萄糖的量的比值为(坑B,只能用单位时间内CO,的释放量表示呼吸速率标号)。C.随着处理时间的延长，核桃幼苗根系呼吸速率逐渐升高A.1:4B.1:3C.1:2D.1:1D.单独施用NH-N的核桃幼苗根系呼吸速率高于单独施用NO-N的(4)某生物兴趣小组在做酵母菌发酵实验时，先通氧，后隔氧，发现产生的酒精量比一直隔氧情况下产生的酒精量多，主要原因是13.(13分)蓝莓果实中富含花色素苷、维生素等，具有抗氧化、抑菌和抑制肿瘤生长等作用。某研究小组为研究蓝莓枝条不同部位的耐低温能力，利用人工模拟低温胁迫的方法得到如下实验第Ⅱ卷（非选择题共40分）结果（注：总呼吸强度用耗氧速率表示）。请回答下列问题二、非选择题（本大题共3小题，共40分。）(1)O2在细胞呼吸中的作用是11.(13分)图1为两种细胞代谢过程的示意图。转运到神经元的乳酸过多会导致其损伤。研究与生物体外燃烧相比，有氧呼吸具有不同的特点，表现在发现，Rhb蛋白能促进丙酮酸进人线粒体氧化分解供能。请回答下列问题：窗白元和↑(写出两点)凤履，-两南煎分一收质细胞(2)该实验必须在黑暗条件下进行，原因是温设m据图可知，1年生茎尖较1年生茎基对低温胁口乳酸含量迫更加敏感，判断依据是酚丽神经元(3)随着温度的降低，蓝莓1年生枝条尖端（茎尖）、1年生枝条基端（茎基）和2年生枝条（茎运动强亚的呼吸速率都会下降，原因是图21)据图1可知，在线粒体内氧化分解的物质有图中的自由基会攻击·12·【24·G3ZC·生物（六）-R-必考-SX)

L enhs0n Douyne Chneseof thevidingTikTok,and many have tuedntL moved by the hospitality)fkof thepeople in Wuhan,and said they are always helpful and supportive.ficom the ocagovemofWuhan fis hmtopromothe carryingo of preferential (policies.Liu opened his second branc the end of ast year.He plans to expand morewhen the opportuntyisHe said his decisionouruiserepreeriadream inWuhan was right.Wuhan isa city with huge consumtion potential,nice peope and supportive goverment,s Liuwould choose Wuhan again if he had to do it over.24.Where did Liu Tzu-wei first launch his business?A.In Wuhan.B.In Taiwan.C.In London.D.In Hangzhou.25.How would Liu feel about the future of his milk tea shop?A.It's unexpected.B.It's hopeful.C.It's challenging.D.It's regretful.26.What can we learn from the passage?A.All the fans have turned into customers.B.Liu's business was an instant hit in Wuhan.C.Liu worked as an e-shopping agent after graduation.D.Liu's business has received assistance from the government.27.What message does the story convey?A.Well begun is half done.B.East or west,home is best.C.Victory belongs to the most persevering.D.He that travels far knows much.CTake the wheel of an electric vehicle and prepare to be amazed.The latest technology is there,withtablet like screens instead of old-fashioned switches.Add falling price which make owning and runningmany electric vehicles as cheap as fossil-fuel alternatives,and the open road signals.Above all,the instantacceleration of battery power makes driving easy and exciting.EV should be recharged roughly every 250 miles.When you do find a public charging point,it issometimes inaccessible,which cause "range anxiety It is one of the main reasons drivers give for notbuying an EV.Who might install them?Drivers will need a mix of fast"long distance"chargers installednear motorways and ower"tpup"chargers available in the car parks of shopping centers,restaurantsand so on.Dedicated charging firms and carmakers are investing in infrastructure )Oil com-panies are putting chargers in petrol stations and buying charging companies.Yet the charging busines suer from big problems.showtoadjust between the planning auhorities and grid(ms.Another is the osTstthPos may bediffcu t ttain becausethe etrkswill ot at st be heaviyusd.reatediskthat the coveewill have gaps.nd thethereistheu of cmetingrvshoulbe ble wthomherwithout having to sign up to them all.What todo?GovesA well a fnding EV mayare thrwing h atpublic harger mericad50i by.B pstorequirewulheethe problem of cvnve will remain.28.Which is the biggest highlight of an EV?A.Falling price.B.Replacing switchesC.Running self-drive.D.Instant acceleration of battery power.29.What do the underined wordsange anxiety"n Paragraph 2 refer to?Y高三模拟卷（八）：英语·A区专用，第4页（共八页）】

BreakBackspace新课程高三第40期总19081期2022年4月5日星期二ey国内统-刊号CN14-0702/(F)网址http:/ww.xyybs..com配套教学PPT)六)分150分)听第9段材料，回答第14至17题。14.What is the probable relationship betweenthe two speakers?A.Couples.B.Colleagues.C.Neighbors15.Why did the man miss watching the movie?A.He fell sick.B.His eyes hurt.C.He had a sleep.6.What type of show does the public never gettired of?A.Game showsB.Talk shows.C.Situation comedies.7.Which channel is the sitcom on?A.Channel 5.B.Channel 9.C.Channel 11.听第10段材料，回答第18至20题。What do people with FOMO worry about?A.Living a busy life.BMissing out on happy things.

2.原子核核外电子正质子中子(6)硅Si质子数核外电子数质子数中子数(7)磷P听写17原子核外电子的(8)硫S(合理即可)排布离子的形成3.质子数（或核电荷数）氧、硅、铝、铁+12+64.元素分子原子离子听写19元素符号元素周期表①①游四@洲1.氢H锂Li氦He氮N碳C2.163得到氧O氟F.镁Mg钠Na氖Ne3.分子原子离子分子原子离子铝A1硅Si磷P硫S氯CI听写18元素氩Ar钾K钙Ca1.(1)钠Na2.核电荷数质子数核外电子数(2)镁Mg3.①原子序数(3)铝A1②元素符号(4)钾K③相对原子质量(5)钙Ca④元素名称(6)铁Fe听写20爱护水资源(7)铜Cu加热(8)锌Zn(合理即可)1.①高锰酸钾锰酸钾十二氧化锰十氧气2.(1)氢H②氯酸钾二氧化锰氯化钾十氧气加热(2)碳C二氧化锰(3)氮N过氧化氢水十氧气(4)氧02.淡水节约用水防治水体污染工业(5)氯C1农业生活44化学九年级上·RJ·河南

参考答案及解析化学2022一2023学年度第二学期五校联盟高一期末联芳化学参考答案及解析一、选择题须按要求服用，否则损害身体，B项错误；一定温度1.C【解析】木简的主要成分是纤维素，A项正确；“狼下，钛变得活泼，易被氧气氧化，因此制钛时，要用稀毫”指的是黄鼠狼尾部的毛，毛的主要成分是蛋白质，有气体作保护气，C项正确；焚烧废旧塑料会造成污B项正确；石墨烯是由碳元素组成的单质，属于新型染，不符合绿色化学理念，D项错误。无机非金属材料，C项错误；碲化镉能将光能转化为：7.D【解析】S与O2反应只生成SO2,A项错误；SiO2电能，属于新型无机非金属材料，D项正确。与水不反应，B项错误；C2H6与水不反应，C项错误；2.C【解析】二氧化硅具有良好的光学特性，可用于制丙烯发生加聚反应生成聚丙烯，D项正确。造光导纤维，与其硬度大无关，A项错误；NaHCO,能8.A【解析】甲烷是正四面体结构，四个氢原子是等效与盐酸反应从而起到中和胃酸的作用，B项错误；的，故一氯代物只有一种，新戊烷碳原子的骨架也是NH4HCO3受热易分解，产生大量气体，使面团疏松、正四面体结构，故四个甲基也是等效的，即12个氢原多孔，C项正确；人体不能消化纤维素，纤维素不能为子是等效的，A项正确；氢氟酸能溶解SO2,与酸性人体提供营养，D项错误。强弱无关，B项错误；A1C13是共价化合物，不能用于3.B【解析】锂位于元素周期表第IA族，故碳酸锂的冶炼铝，C项错误：SO3与H2O反应为不可逆反应，D化学式为L2CO3,A项正确；碳酸锂与酸可以反应，项错误。与某些碱（如氢氧化钙）也反应，B项错误；锂和钠的衣焰色试验颜色不同，可通过焰色试验鉴别碳酸锂和碳9.B【解析】CHOH的结构式为H一C一O一H,含有酸钠，C项正确；碳酸锂既含有离子键，又含有共价少键，D项正确。五对共用电子对，A项错误；该反应为放热的氧化还4.C【解析】CHCl3俗称氯仿，A项正确；CHCIF2的原反应，能用于设计成甲醇燃料电池，B项正确；该反结构类似于甲烷，为四面体结构，故不存在同分异构应为放热反应，反应物的总能量大于生成物的总能体，B项正确；C原子半径大于F原子半径，C项错量，C项错误；CH3OH与CH3CH2OH互为同系物，误；反应为加聚反应，D项正确。化学性质相似，D项错误。5.B【解析】豆类植物的根瘤能将空气中的游离态氮10.B【解析】由石油提炼柴油是利用了分馏的方法分转化为化合态氮被植物吸收，实现自然固氮，A项正离得到不同沸点的物质，A项不符合题意；制玻璃的确；废旧电池含有重金属，掩埋会污染土壤，应收集集过程中石英砂和石灰石高温条件下反应生成硅酸钙中处理，B项错误；用导线连接铜片和铁片，分别插入和二氧化碳，该反应是高沸点物质制备低沸点物质柠檬中，该装置形成了简易的原电池，该电池可将化的反应，与元素的非金属性无关，B项符合题意；常学能转化为电能，C项正确；乙酸具有酸性且酸性大温下，浓硝酸与铝发生钝化反应，陈述Ⅱ错误，C项于碳酸，可以清除水壶中的少量水垢，D项正确。不符合题意；制作水果罐头时添加适量的维生素C,6.C【解析】苯分子不含碳碳双键，A项错误；药物必是因为维生素C具有还原性，能作抗氧化剂，D项不

2022~2023学年下学期高二年级期末联考卷·化学参考答案、提示及评分细则1.C聚氨酯属于有机物，陶瓷、镁铝合金、碳纤维均属于无机材料，C项符合题意。2.B电负性最大的是O,B项正确。3.AFS为难溶性固体，不能拆开，B项错误；CH COOH为弱酸，不拆开，C项错误；电荷不守恒，D项错误。4.C由水电离出来的c(OH)=1.0×10-13ol·L1的溶液应为酸或碱性水溶液，C项为中性，故不可能。5.C水中含有H,A项错误；标准状况下，CCl4为液体，B项错误；每个HS中含2个孤电子对，故1molH2S中含孤电子对数为2NA,C项正确；C2与水发生可逆反应，D项错误。6.B容量瓶不能用来稀释溶解物质，A项不符合题意；氨水滴入氧化钙，氧化钙和水反应放热，使氨水分解生成氨气，可以制备少量氨气，B项符合题意；分离时，温度计水银球应在支管口处，C项不符合题意；CO2和HCI都可与碳酸钠溶液反应，D项不符合题意。OH7.D非金属性：CI>S,故酸性：HCIO4>HSO4,A项正确；具有酸性，而OH不具有酸性，B项正确；一CC极性强于CHC2,CC1COOH中羧基中羟基的极性更大，更易于电离出H+,酸性：CL3 CCOOH>C2 CHCOOH,C项正确；电负性：F>Cl,一CH2F极性大于CH2Cl,故酸性FCH2COOH>CICH2 COOH,D项错误。8.A制备金属钠用电解熔融NCl,B项错误；制备金属铝，电解熔融的Al2O3,C项错误；制备金属铜，应用还原法，D项错误。9.B分子中含有羟基和羧基两种官能团，A项正确；分子中的碳原子为$p、sp杂化，B项错误；醇羟基能被酸性高锰酸钾溶液氧化，C项正确；分子中含有羟基和羧基，均能与金属钠反应，羧基也能与NOH溶液反应，D项正确。l0.C根据题意知，W、X、Y、Z分别为O、Na、S、Cl。简单离子半径：W>X,即O->Na+,A项错误；X与Z形成的NaCl为离子化合物，B项错误；最简单氢化物的沸点：W>Y,C项正确；第一电离能：Z>Y,D项错误。1l.B单质Fe是金属晶体，含有金属键，A项正确；基态Fe原子核外电子排布式为[Ar]3d4s2,B项错误；由晶胞图，根据均摊法可知，C0与Ni原子个数比为3：1，C项正确；Co与Ni之间的最短距离为面对角线的一半即受&m,D项正确。12.B电极失去电子，故应与电源的正极相连，A项正确；可传导O-,说明是非溶液环境，B项错误；电极b的电极反应式为O2+4e=2O2,C项正确；a极的电极反应式为SO2一2e十O2-=SO3,每生成0.5 mol SO3,转移1mole,D项正确。13.A镁与稀硫酸反应放热，A项正确；该溶液中不一定含有Ag,也可能含有SO,B项错误；铜粉与稀硝酸反应产生大量NO,C项错误；颜色变浅原因是苯萃取了溴水中的溴，D项错误。【高二年级期末联考卷·化学参考答案第1页（共2页）】232755Z

W:Do you want to watch a movie tonight?I have a lot of new ones.M:I have to do my homework and then eat dinner with my family.But I can come over after that.W:Great.I have all the recent ones.I just got the new Star Wars movie.We could also watch Frozen II or NeZha.M:Oh,I really wanted to see Ne Zha.It is still hard to find,though.How did you find these new moviesalready?W:I downloaded them for free.M:You shouldn't do that.Filmmakers work very hard on making these movies.Unless we buy them or seethem in theaters,the movie industry can't continue to exist.We need to support the filmmakers.听下面一段对话，回答第14至第16三个小题。现在，你有15秒钟的时间阅读这三个小题。(Text 9)W:Good morning,Beautiful Smile Dentistry!How may I help you?M:Good morning,I'd like to schedule a check-up.W:I'd be happy to do that for you.Have you been to Beautiful Smile before?M:Yes,I have.My last check-up was six months ago.W:Great!Can I get your name,please?M:Of course.My name is Steve Cook.W:Thank you,Mr.Cook.Which dentist did you see on your last check-up?M:I'm not sure,really.I'm a bit forgetful.W:That's OK.Let me check your chart.Oh,it's Dr.Lee.He has time next Thursday morning.Is that OK?M:Hmm,that's not good.I've got to work.How about the next day?W:OK.Would you like to suggest a time?M:Does he have anything open in the afternoon?W:Yes.We could fit you in at 2:30 in the afternoon.M:Great.That'll work.W:OK.Thank you for calling,Mr.Cook!We'll see you next week.M:Thank you！Bye-bye！听下面一段独白，回答第17至第20四个小题。现在，你有20秒钟的时间阅读这四个小题。(Text 10)W:Welcome to the introduction to the London Tea Trade centre.Now,look at this picture.It's the Lon-don Tea Trade Centre.As you can see,it is on the north bank of the River Thames.It is the center of animportant industry in the everyday life of the British people.Tea is the British national drink.Every man,woman and child over ten years of age,has an average over four cups a day,or some one thousand five hundredcups annually.About 30 percent of the world's export of tea makes its way to London.And Britain is by far thelargest importer of tea in the world.Now in the second picture,you can see how tea is tasted in the Tea Trade Centre before it is sold.Here,different types of tea are tasted by skilled teatasters before they are sold at each week's tea sale.It's amazing tosee them at work!Over a hundred kinds of tea are laid out in a line on a long table.The tasters generally tastetea with milk,since that is how the majority of British people drink their tea.The tasters move down the linewith surprising speed,tasting from a spoon and deciding what is a fair price for each tea.第二节到此结束。现在，你有两分钟的时间将试卷上的答案转涂到答题卡上。听力部分到此结束。【高一英语·参考答案第3页（共4页）】·22-12-283A·

学生用人书名师导学·选择性考试第一轮总复·化学数，W、Y、Z的最外层电子数之和为11且数之比为1：1：1。若在各自的水溶液答题Y、Z的最外层电子数相差1。下列说法正确中，A能抑制水的电离，B能促进水的电案号的是离，则A的化学式为,B的化1A.W的氢化物的沸点比Z的氢化物的沸学式为2点低10.A、B、C、D、E五种元素中只有E为金属元3B.W与Y可形成化合物Y4W素，五种元素的原子序数按B、D、C、A、E的4C.Z与X在自然界中形成不溶于水的离子顺序依次增大，D、C元素在元素周期表中5化合物位置相邻，在一定条件下，B的单质可以分D.W与X只能组成两种化合物别和A、C、D的单质化合生成甲、乙、丙化二、非选择题合物，C的单质和D的单质化合可得丁，9.元素X、Y、Z、M、N均为短周期主族元素，且戊、己、庚均为化合物。已知乙、丙每个分原子序数依次增大。已知Y元素原子的最子中均含有10个电子，下图为相互转化外层电子数与核外电子总数之比为3：4，M关系：元素原子的最外层电子数与次外层电子数甲之比为3：4，且M原子的质子数是Y原子A的单质区风留克行的2倍；N、Z、X+的半径逐渐减小；化合已的单质庚物XN在常温下为气体。据此回答下列E的单质问题：(1)下面是元素周期表的一部分，请将A、(1)写出Z与N形成的化合物的电子式：C、E用元素符号填在相应的位置上。(2)X与Y可分别形成10电子和18电子的分子，写出该18电子分子转化成10电子分子的化学方程式：(2)写出A的最高价氧化物对应水化物的(分解反应)。化学式(3)如图表示由题述元素组成的两种气体分(3)戊的分子式为。B与D形成子在一定条件下的密闭容器中充分反应的原子个数比为2：1的化合物中，D原前后的转化关系，请写出该转化过程的子最外层为8电子结构，请写出该化合化学方程式：物的电子式：(4)A、B、C、D四种元素原子半径大小顺序609为(用元素符号表示)。ong°3(5)A、B、D三种元素形成的化合物中，含有(●代表M原子O代表Y原子)化学键的类型为(4)A、B均为由题述五种元素中的三种元素组成的强电解质，且组成元素的原子个426

WRITINGOne possible version:September 23 FridaySunnyIII.1.beautiful2.were made 3.truthI was excited to have my first dough figure4.visited5.interesting 6.actuallyclass today.We learnt about the materials and7.himself8.products9.to avoidtools first.To make dough figures,dough,food10.morecolorings,and scissors are needed.Then theteacher taught us how to make a dough tiger.Itwas a little difficult,but I had great fun in thewhole making process.Section B同步练1.completed2.lively3.liveliest岩养淫报社4.completely5.readingEARNINGENGLISH能力提升基础训练九年级山西第5期I.1.its2.forms3.scissors能力提升4.balloons5.international(Unit 5)情景反应1-5 BABCCII.1.paper cutting2.are sent out听力部分.A3.turned into4.slowly rose into5.at a high heatIII.1.ask for help 2.other celebrations3.bamboo4.good wishes5.red paper6.flowers7.new year8.very real9.fire10.life and beautygASelf Check听力材料基础训练A.1.ago2.in3.to01 M:What was the old man doing when you saw4.were5.to6.buthim?7.each8.than9.whatW:He was sleeping on the grass.10.themB.1.began2.more important3.memories4.was taught2 M:What kind of books would you like to choose?5.their6.differentW:Well,I'd like to buy a fairy book for my little7.carefully8.to makesister.9.performance10.traditional®3 W:How is the weather today?M:It is a little cold.You'd better wear gloves第4版READINGwhen you ride to school.4 M:I plan to go on a trip to Japan next month任务型阅读Have you ever been there?W:Not yet,but I heard that it is a clean and1-5 EFCADbeautiful country.5 M:There is a book fair in the park.Would youlike to go with me tomorrow?W:Sure.I want to buy some novels there.

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第四章非金属及其化合物2.(2022山东菏泽期末)煤、石油、天然气是重要的B.氧化钙：吸氧剂化石能源，下列有关说法正确的是C碳酸氢钠：膨松剂A.甲烷与足量的氯气发生取代反应，产物只有D.阿司匹林：解热镇痛药四氯化碳和氯化氢4.(2022湖北武汉期末)下列关于医药和食品添加B.焦炉气是煤干馏的产物之剂的常识性介绍，说法错误的是C.汽油、煤油等都是石油裂化的产品A.亚硝酸钠有一定的毒性，还会与食物作用生D天然气的主要成分是甲烷，它是可再生能源成致癌物，因此不能用于肉制品的生产3.(2022河南开封联考)下列关于金属冶炼的说法B处方药需要凭医生处方才能从药店获得，并正确的是在指导下使用A.电解法获得镁时，可在C02或N2中降温冷却C缓释药物可以减少每天吃药的次数，方便了B.热还原法常用的还原剂有C0、H2、C、Al等人们的药物使用C.金属Na、Mg、Al均能通过电解熔融氯化物D.合成色素的着色力强，稳定性好，成本较低，的方法获得因此部分合成色素可以在食品加工过程中D.人类历史上金属被发现的顺序与金属的活添加泼性无关考点三环境保护与绿色化学考点二化学品的合理使用考向1环境问题与环境保护考向1化肥、农药的合理施用1.(2022江苏淮安期末)2022年世界环境日的主1.(2022湖南长沙期末)化肥和农药对农业的增题是“共建清洁美丽世界”。下列做法不应提产、增收起着重要作用，但施用不当也会给人倡的是类和环境带来危害。下列关于化肥或农药的A.推广电动汽车，践行绿色交通施用描述不正确的是(B.拒绝露天烧烤，合理健康饮食A.对于已结块的硝酸铵，敲击粉碎后施用C.秸秆就地焚烧，增强土壤肥效B.磷肥的大量施用可能造成水体富营养化D.净化工业尾气，减少雾霾生成C.复合肥料能同时均匀地供给作物几种养分，2.(2022河北唐山期中)环境污染问题越来越受到肥效高人们的关注，造成环境污染的主要原因之一是D.有害农药的滥用会导致粮食、果品、蔬菜等人类生产活动中过度排放有关物质。下列环境的污染问题与所对应的物质描述不正确的是()2.(2022辽宁大连期中)合理施用化肥，有利于农A煤等化石燃料的燃烧常伴随着大量烟尘作物生长和减少环境污染，下列有关化肥说法C02、S02和氮氧化物等有毒物质的排放正确的是B.臭氧层破坏主要是因为人类大量使用的制A.要大量施用化肥才能够获得高产冷剂，如氟利昂等B.氯化铵与熟石灰混合施用，既施了氮肥又改C.S02、NO2均可以产生酸雨良了酸性土壤D.光化学烟雾主要是由汽车、工厂产生的NO:C硝酸钾属于盐，是复合肥料等引起的一种有毒烟雾D.所有化肥都能溶于水考向2绿色化学考向2合理用药安全使用食品添加剂3下列实验或叙述中，不符合绿色化学理念的是3.下列物质与用途对应不正确的是A苯甲酸钠：食品防腐剂A.用乙醇汽油代替普通汽油作汽车燃料·99·

参考答案及深度解析50.B【解析】考查形容词。由空后一句“You'll soon be facing63.to offer【解析】考查非谓语动词。分析句子结构可知，本the best of the best in the county bee.”可知，姐姐告诉作者以句已有谓语动词helped,且句中没有连词，所以空处应填所后会遇到更强的对手的，所以此处是提醒作者不要那么骄给词的非谓语形式。由句意可知，此处表示目的，所以应用傲。upset意为“不安的”；proud意为“自豪的，骄傲的”；动词不定式。故填to offer。.anxious意为“着急的”；frustrated意为“沮丧的”。故选B。64.families【解析】考查名词的数。由句意可知，此处泛指来51.D【解析】考查动词。根据下文“I am the alpha-best with no自贫困家庭的女孩，所以空处应用名词的复数形式。故填efforts at all.”可知，作者认为自己是最棒的，所以此处表达families。的是，其他拼词选手比不上他。admire意为“羡慕”；pass意65.has changed【解析】考查时态。由时间状语“Since its为“通过”；influence意为“影响”；match意为“与…相匹opening in2O08”可知，该句应用现在完成时(has/have敌；和…不相上下”。故选D。done),且主语she是第三人称单数，所以此处的助动词需用52.C【解析】考查动词。由上文的“After six rounds'”及下文的has。故填has changed。“from more than 100 to just seven”可知，经过了六轮比赛之知识拓展现在完成时中常见的时间状语后，学生数从100多人减少到只有7人。jump意为“跳跃”；rise意为“上升”；decrease意为“减少”；spread意为“传播，(1)“for+时间”：for后面可以直接加时间数字表示时间，如along time,several days,some time等。蔓延”。故选C。53.D【解析】考查名词。根据下文中的“Unfortunately,I(2)“since+表示过去时间的单词或句子”：表示过去某时开crashed with the word maestro at last..”可知，作者最后撞上了始的动作或者状态一直持续到现在。“maestro”这个词。所以此处表达的是，如果让作者拼写“航(3)现在完成时常常与表示不确定的过去时间状语连用，如空航天”或“圆锥形”这样的词，他就会创造历史。这与后文already,yet,just,before,recently,lately等（注：:already常用的Unfortunately才能形成对比。concern意为“担心”；effort于肯定句，yt常用于否定句或疑问句中，且常位于句末)。意为“努力”；promise意为“承诺”；history意为“历史”。故(4)现在完成时常常与表示频度的时间状语连用，如often,选D。sometimes,ever,never,twice,once,rarely,three times,onseveral occasions等。54.C【解析】考查形容词。根据上文可知，作者没能拼出·Have you ever been to the Great Wall?你曾经去过长城吗？“maestro”这个词，所以作者呆呆地站在那里很长时间。harmed意为“受伤害的”；devoted意为“投入的”；frozen意为(5)现在完成时还常与包括现在时间在内的时间状语连用，“冷冻的，僵住的”；addicted意为“上瘾的”。故选C。now,up to now,during in the past/last few days/weeks/months/years,so far等。55.C【解析】考查名词。根据下文中的“with a small bow”和“and then shook hands with the runner--up(亚军)”可知，最终66.suffering【解析】考查动名词。prevent sb(from)doing sth的获胜者与作者之前的行为是正相反的。role意为“角色”；为固定搭配，意为“阻止某人做某事”。故填suffering。way意为“方法”；opposite意为“对立的人（或物），对立面，67.that【解析】考查宾语从句。分析句子结构可知，动词say反面”；behavior意为“行为”。故选C。后需接引导词引导宾语从句，从句结构完整，所以空处需用56.A【解析】考查名词。根据上文语境及常识可知，在比赛最引导词that引导宾语从句。故填that。后，应给获胜者颁奖杯，且空处与上文“The trophy（奖68.but【解析】考查连词。由空处前后的句意可知，前后句之杯)was presented to me.”一句中的trophy是原词复现。故间是转折关系，所以空处需用连词but。故填but。选A。69.deeply【解析】考查副词。空处修饰动词touched,所以应57.B【解析】考查动词短语。根据下面一段作者的表现和空用副词作状语。故填deeply。前的“I got to know Deandra's words”可知，作者此时是明白70.a【解析】考查固定短语。“make a/an+ad.+difference了姐姐的话，觉得她的话有道理。take place意为“发生”；to”为固定搭配，意为“对…产生…影响”，real是以辅make sense意为“有道理”；come out意为“出版，发行”；catch音音素开头的单词，前面应用冠词a。故填a。up意为“赶上”。故选B。第四部分写作58.D【解析】考查动词。根据后文作者说的话“I'm sorry I was第一节so impolite when I won..”可知，作者应是向Alexa道歉。relateHealth意为“联系”；occur意为“发生”；contribute意为“贡献”；Ladies and gentlemen,apologize意为“道歉”。故选D。I'm honor to share the topic "health"with you.As the59.A【解析】考查名词。根据下文中的“Lt'shonoredon it,partner.”一句可知，Alexa问作者需不需要一个学伙伴。saying go,health is above wealth.You must feel the samegoes空处与后文中的partner是原词复现。故选A。way.Without health,we can't achieve that we set out to do.60.D【解析】考查动词。根据下文中的“shaking my hand”可what知，Alexa应是和作者握手。let's shake on it为固定表达，意With health,how can we catch up with the rapidly changed为“握手确认（达成共识）”。故选D。Withoutchanging第二节world?In brief,health is anything.everything体裁：记叙文主题：人与社会一时代楷模张桂梅To keep health,we should have a balanced diet,form good【语篇解读】本文主要讲述了云南省丽江市华坪女子中学创始人healthy兼校长—张桂梅的故事。living habits,take on enough exercise and keep a good state of61.wh0【解析】考查定语从句。分析句子结构可知，空处引导mind.In conclusion,I personal believe a healthy life is the source的是非限制性定语从句，先行词是gl,指人，且空处在定语personally从句中作主语，所以应用关系代词wo引导该定语从句。故of happiness.So let's keep A eye on our health and enjoy a healthyan填who。life.Thank you.62.traveled/travelled【解析】考查时态。由时间状语in第一处：honor-→honored【解析】考查固定短语。be动词后面1957可知，该句应用一般过去时，表示过去发生的事情。故应用形容词作表语。be honored to do sth为固定用法，填traveled/travelled。意为“做某事感到荣幸”。故将honor改为honored。D9卷2·英语

ENGLISH(上接第14版中缝)Well,plaviolf used to be myEARNINGfavorite hobbyBut now I spend学关诉thestENGLISHhebyPdre55ea9(上接第2版)Have you got any other hobbies?ant comprehension questions.M:Um.I guess I enjoy playing.ts'screens at once and gaugemlnecopueganetee第二节（共5小题；每小题2.5分，满分12.5erehplynheadditional support.They alsoames and me make new阅读下面短文，从短文后的选项中选项。选项中有两项为多余选项。lessonsfriend Hoy youend muchochildren reach proficiency inW:Well,I'm not interested in computerAcademic conferences are an essential partat I am doing can really makegames.I think there's no sensein spending time playingattending academic conferences is helpfulth it.somethingsrar()with the opportunity to listen to different pohe closure?eerch eto face withmy friends.more great people.There are countless bM:Ilike chrndsconferences.W:Oh,itm cassouEnglish teacher is cominAfter37 If you want to know about thehe closure.class inoue you to someof my friends.(17)before they are even published in journaleading ability.Text 10dents improve their readingHello veryone and welcome toto be.Many researchers will present finour company.My name is Jamespublished at a conference.Brown and Iwork in the HRYour journey to a new place for a coown problems.department.I'm the informationofficer.(18)Now,I'd like to giveher students'needs.you a short introduction to my jobnew place,you may eat new food,visit loxercises more interesting.and also to explain the programfor the day.I'm in charge of alla new language and make some good frieg tests before each class.communications.And I'm also your39 Giving a talk or presentatioParagraph 4 probably mean?guide for the day,so please ask meif you have any questions.As youin front of an audience.And you'll learnControl.D.Change.can see from the program,wehave a tour of the production areascribe the author?with Kim Taylor,our productionResponsible and flexible.manager,then lunch at 12:30.(19)After lunch we have a video to showHumorous and considerate.you at 2:00,then a meeting with John第一节（共15小题；每小题1分，满影White,our marketing manager.Forthis evening we have booked dinnerat 8:00 at the Six Seven,a wonderful阅读下面短文，从每题所给的Arestaurant in the town center.We'llcollection and say,'Oh,thesemeet at your hotel at 7:15 and walk人空白处的最佳选项。Wallace says."The artists putthere.(20)Right,that's all I want tosay.Does anyone have any questions?The tech industry created manyfor the price that they shouldOK,thank you for listening.NowI'm going to hand it over to Kim.So.how they are used by kids,they usuallyhave a good day!My kids 42 iPhones very earlyrecently?本期参考答案husband and I 43 after we got new本期第1-4版1-5AABCB6-10 CBACBlearned the English words on her ow11-15 ABABB16-20 CABCA21-25 BCADB26-30ABBCBwas 44 by simple apps that couldr31-35 DDACDly show?41-45 CBDAC36-40 FAGCDchildren's stories to her.At that time,51-55 BACBD46-50 DABDC57.listed56.whichusually permit her to use iPhone as aerson.59.living58.has droppedThings were good for a few yeaworld.G60.earlier61.undoubtedly62.ins a traditional art piece.63.awas 47 the first time I caught her w65.volunteers64.to enrich

肼燃烧放出的热量为534k,故该反应的热化学方程式为N2H4(g)+O2(g)一N2(g)+2H2O(g)△H=一534k·mol1,A正确；燃烧热是指生成稳定的指定产物所放出的热量，但水蒸气不稳定，B错误；由N2H4(g)+O2(g)一N2(g)+2H2O(g)△H=-534k·mol1,可知该反应是放热反应，所以1molN2H4(g)和1molO2(g)所含能量之和高于1molN2(g)和2molH2O(g)所含能量之和，C错误；化学反应实质是旧键断裂和新键生成，旧化学键断裂时需要消耗能量，且两个过程能量不相等，D错误。5.C解析：用环形铜质搅拌棒替代环形玻璃搅拌棒，将增大热量的散失，故测得中和反应的△H偏高，A错误；由题干信息可知，HF是弱酸，且电离过程中吸收热量，故HF(aq)+NaOH(aq)一NaF(aq)+H,O(I)的反应热△H>-57.3kJ·mol-1,B错误；为了减少热量的损失，减小实验误差，向内筒加料时，应一次性快速加入且立即盖紧杯盖，C正确；增大反应物溶液的体积，放出的热量同倍数增大，但测得的中和反应的反应热数值不变，D错误。6,A解析：根据盖斯定律，由反应①×号+反应②×号2反应③X2=反应国，则△，=△H,×号+AH,×号△H,×2=号(aH,+AH,-3aH>.故选A.7.C解析：相同条件下半椅型结构能量最高，最不稳定，A正确；扭船型结构转化成椅型结构要释放能量，△H<0,一定条件下可自发转化，B正确；CH2(椅型)→CH12(船型)△H=十28.9kJ。mol1,C错误；椅型转化成扭船型是吸热反应，△H>0,正反应的活化能大于逆反应的活化能，D正确。8.B解析：该过程是利用太阳光实现高效分解水，所以该反应中太阳能转化为化学能，A正确；反应I是水反应生成氢气与过氧化氢，涉及到O一H键的断裂、O一O键和H一H键的形成，B错误；反应Ⅱ是过氧化氢转化为水与氧气，反应过程可表示为2H,0催化剂2H0+0,◆，光C正确；反应I是水反应生成氢气与过氧化氢，反应Ⅱ是过氧化氢转化为水与氧气，CN、CQDs为反应过程中的催化剂，总反应为2H,09NCQD2H,↑十0.+，D光正确。9.C解析：由图可知，CO(g)+2H2O(g)的相对能量为0，C02(g)+H2(g)十H2O(g)的相对能量为-0.72eV,生敖学笔记

34.What can we learn from the passage?第二节阅读短文，根据语篇要求填空，使短文通顺、意思A.The documentary Top Land is more popular than On完整。每空限填一词。the Road.四A mouse saw a bucket (of corn.There was a small hole in the阅B.The couple went to the Amazon rainforest to avoidbucket.The mouse was hungry,so he got into the bucket through the holeCOVID-19.and ate much cornC.The couple seldom attended international meetings onBut he failed ta6 leave the bucket because his belly (waseducationIt wasn't the first time that they had visited the Amazontoo big.The mouse started crying.A rabbit passed by and asked why.The理解mouse said,"I got into the bucket through the hole.Now I can't go outrainforest.35.What's the purpose of the passage?填because my belly is big”“Wait your belly becomes smal,”said theA.To explain why the Chinese couple took the trip.rabbit and then she left.The mouse fell asleep in the bucket.The next morning.his bellyB.To advise people to take a round-the-world trip.was small.But he was hungry again.He forgot everything and ate moreTo introduce the couple and the documentary Topcorn.Ag a result,he couldn't leave the bucket again.At that moment,Land.D.To look for people who want to take a trip with the_cat found the mouse and ate him.When the rabbit learned aboutthat,she shook her head and said,“Greed(贪婪)is the cause of manycouple.nisfortunes(不幸).”A:Hi,Joe.I love your photos of polar bears.(71)The word comes from Greek with"phil'meaning"a lover of and"math"meaningWhere did you take themHumans are all philomaths to some degree..We want to understand五B:I took them in the Arctic(北极地区)A:Wow that's amazing When did you go there?阅the world Our brains give us the ability to learn throughout our livesThough many people love learning.there are plenty who can't standB:(72)I went there three years agoMy father took meit.Lots of people remember their school days as being boring or even补there arwe stayed there for about half a month.It was really excitingpointless.Scientists have suggested that if an idea is boring,itA:(73)Why do you like the Arctic so much驛becomes harder to connect old ideas with new ideas together.ThisB:I like the Arctic because I think it's the cleanest place in the world.Andnegative(消极的)experience of education at school may lead to peopleavoiding learning opportunities in later life.So.don't let a bad educational experience prevent you learning something对Aouyou oen see polar bears thereB:Yes,we could.Polar bears are the most active between March and Maynew.Evolution(进化)hasmmC(内s的)phitomath.4长elong eamers and try to discoveroWe went there in April and could often see themA.Why is this?A:Sounds great.I wish I could go there one day.B We're interested in eveB:I plan to start my next journey to the Arctic with my father next yearC.Who knows whatwe can achieve?Would vou like to ioin us?D.It means a person who loves to study.A:(75)Yes,I'd like toI need to makeE.Therefore,we will lose interest and get less informationpreparations nowhson was on the vway.Kelly couldn't 41 to race on the假如你是王丽，你的英国笔友Toy最近在交友方面遇三六到一些困惑。不久前，他发来邮件向你寻求帮助。请你给他回一封邮件。词数不少于100（开头和结尾已给出，不计入总词数)。完形填空aDear Wang Li,面have a good friend at school.He is active.And he is friendly and helpfuI knowy that'sto everyone.I'm proud of being friends with him.However,my parents51said "Rut it sounde likews for vour teamKelly thedon't allow me to play with him because he isn't good at study.They askd being the fastessheared moreabout theme to make friends with"good kids".In their eyes,"good kids"are thoseked them to play a gangot the ball and53passed it to Kelly.Then Kelly kieked it hard towardsstudents with high scores.This troubles me deeply.Should I listen to themhecan beYours,Thankswe pullgTonyre rightthaSesaidC41.A.agreeB.expectC.waitD.standD 42.A.usB.herC.himD.themC43.A.coachB.managerC.runnerD.leaderDear Tony,B44.A.busyB.silent.awakeD.healthy六I'm sorry to hear that you have trouble.I'm glad to helpA 45.A.alwaysB hardlvC.sometimesD.neveryou.B46.A.callB.beatC.inviteD.believeB47.A.tiredB.nervousC.happyD.surprisedD 48.A.talk back toB.look back atC.keep away fromD.catch up with面D49.A.disappearedB.attendedC.competedD.laughedC 50.A.imagineB.discoverC.explainD.predictA 51.A.disappointingB.meaninglessC.interestingD.understandingI hope everything will go well with you soon.B.52.A.ballB.teamC.gameD.practiceYours,A53.A.quicklyB.widelyC.luckilyD.clearlyWang LiC.54.A.checkedB.sharedC.scoredD.reportedD.55.A.unlessgB.althoughC.untilD.ifexceawful写作指导：四boy named第一节六本篇作要求同学们写一封邮件，写作重点是解答Before the Christmas holiday I reaa story The Litlest Angel to theToy的困惑，并为他提出一些合理的建议。阅读短文，从class.This ltle angel had in heaven.He语篇©主题：人与社会之社会服务与人际沟通方框中选择适his happy time i⊙子主题：良好的人际关系与社会交往当的词并用其the past.show-and-tell time the next day,David sat in front of©主要时态：一般现在时回主要人称：第一人称正确形式填空，the class with a box."This is my first tooth,"he explained."This is.."He⊙行文布局：空使短文通顺、afraiwhen go表意思完整。每take so that I can always remember you"Knowing th box①分析原因I think your parents do that because they want you to空限填一词，or te dayeparnice and ten pcedget higher scores in tests by making friends with the topWhen the holiday was over.all the students returned to school每词限用一次。except He上students.I have neveremember the"little angel".and his box full of love forever.3

听第7段材料，回答第8至10题。8.What is the woman doing?A.Teaching the baking skills.B.Giving opinions.C.Picking cookies..What oes the womn probably think of the ch cke?A.It's too sweet.B.It's very soft.10.What do we know about the last cookie?C.It's very dryA.The speakers made it.B.The man bought it from a store.余黑。如需改C.The woman got it as a Christmas gift.写在本试卷上听第8段材料，回答第11至13题。11.What is the probable relationship between the speakers?A.Brother and sister.B.Shop owner and customer.C.Former neighbors.12.What has been built in place of the video store?答案转涂到A.A parking lot.B.A cinema.13.Who did the speakers saw in the end?C.A shopping mall.A.A video store owner.B.Mr.Otto.最佳选项。听第9段材料，回答第14至17题。C.The theater manager遍。14.How did the man plan to go to werk today?A.By bike.(B.On foot.C.By car.15.How long was the man late?A.30 minutes.B.45 minutes.C.75 minutes.16.Why was the man extra late?v.bA.He started out lateB.He walked very slowly.C.He was waiting a long time for help17.What does the woman plan to do?A.Ask the man's mother for advice.B.Get the other group members to come laterC.Tell the man the meeting time much earlier next time.听第10段材料，回答第18至20题。18.Why should the dirt be loose?A.To fill the pot more.B.To let the seed spread.选C.To let more sun inHawa53-boo od n19.How does the speaker measure the water?A.By checking the pot.B.By using her fingerC.By counting up.20.What is the talk about?oA.Protecting a tree.B.Growing a plant.C.Finding some apples.【2023高考名校导航冲刺金卷·英语（一）第2页（共8页）】

39.F。根据本空前的You can edit your video.To learn how to edit,I just took online courseson how to use particular editing programs及本空后的Use attractive titles and create a colourfulthumbnail for your video可知，本空内容应与“编辑视频”相关，且在文中起承上启下的作用，F项符合语境。F项中的Once you've edited your video承接本空前的内容，it's all aboutgetting it seen by people呼应本空后的attractive titles和a colourful thumbnail。40.D。根据本空前的every YouTuber will receive a negative or unpleasant comment.Pleaseremember,this is not a reflection of your hard work及本空后的Ignore the negativity and justfocus on the positive comments you receive可知，本空内容应讲述不要因为负面的评论就质疑你的视频，故D项符合语境。语言知识运用第一节主题语境：人与自我一一做人与做事本文是记叙文。文章讲述了护士Jennifer Smith帮助一名空巢老年患者照顾他的宠物狗的故事。41.C。根据文章首句中的an early morning phone call及下文中的‘Boomer is in an animalshelter!'和Iwill.Boomer and take care of him for you可知，Burley很担心他的宠物狗Boomer。42.A。文章首句It was right after Thanksgiving that nurse Jennifer Smith got an early morningphone call from John Burley,one of her patients提示本空选择calling。43.D。根据上文中Burley一大早给Smith打电话的行为及下文中的The60-year-old lived.with Boomer可知，小狗Boomer对主人Burley来说非常重要，world符合语境。44.A。下文中的Iwil.Boomer and take care of him for you及so when he was hospitalized forlung problems,,he had no one to take care of his dog说明Burley想让护士Smith帮他照顾宠物狗，故选take care of。45.C。根据本句中的take care of him for you及下文中Smith寻找小狗Boomer的行为可知，Smith答应Burley自己会找到Boomer,并照顾它。46.A。根据下文中的Most of his family lives in Arkansas,so when he was hospitalized for lungproblems,he had no one to take care of his dog可知，60岁的Burley和宠物狗Boomer独自生活在一起，故选alone。47.D。根据上文中Burley给Smith打电话请求她帮忙照顾小狗的行为及Most of his familylives in Arkansas,so when he was hospitalized for lung problems,he had no one to take care ofhis dog可知，只有Smith可以帮助Burley照顾Boomer,except符合语境。48.c。根据上文的描述可知，小狗Boomer对主人Burley来说很重要。结合本句中的showingoff pictures of his dog可知，Burley经常谈论自己的小狗Boomer,talk about符合语境49.B。根据上文的描述及下文中Smith寻找小狗Boomer的行为和Right now the focus is onBurley getting.and taking Boomer home one day可知，Smith会帮助Burley照顾小狗，等他身体康复后，将它还给他。也就是说，她不会让他们分开的。50.B。上文中的‘Boomer is in an animal shelter!'和下文中的nearby animal shelters提示本空选择shelter。5l.D。本段描述Smith寻找Boomer的过程。根据上文中的Burley didn't know which.Boomerwas in及下文中的she called the Rome Humane Society可知，Smith查询了附近的动物收容所。设空处所填的词应该与“查询”具有相同或相近的含义，故选looked up。52.A。根据上文的描述可知，Smith乐意帮助Burley照顾小狗。结合下文中的She took an earlylunch the next day and drove to the shelter可知，Smith打听到Boomer的下落时感到很高兴。设空处所填的词应该与“高兴”具有相同或相近的含义，故选happy。

广西武鸣高中2024届高三（上)开学调研测试题答案化学一、选择题：本题共15小题，每小题3分，共45分。每小题只有一个选项符合题目要求。题号12345689101112131415答案D BBABCDDDDCDBB二、非选择题：本题共4小题，共55分。16.(除特别注明外，每空2分，共10分)(1)三颈烧瓶(1分)(2)反应液不再分层（或无油珠）(3)①除去多余的高锰酸钾，避免加盐酸时生成有毒的氯气②AC(4)苯甲酸易升华而损失(2分)（5)重结品1分)17.(每空2分，共16分)(1)MnO2+S03+2H=Mn2++S04+H20(2)4.7—5.2(3)2MnCO3+Cu2++H2O=Cu2(OH)2CO31+2Mn2+CO2 1(4)Mg2+2F-=MgF2↓(5)若NH4)2S溶液浓度过大，会生成MnS沉淀，造成产品损失(6)NH4)2SO4和Na2SO4(7)+42a-V(am)+(an)18.(除特别注明外，每空2分，共14分)0.375(1)-49kJmo1(2)①C02(1分)②CD③t④a(a+0.1)(0.14-a)(0.43-a(3)阳离子(1分)(4)C0,+6H++6e=CH3OH+H0(5)6:119.(除特别说明外，每空2分，共15分)（1)酰胺基、醚键(2)BDOHCHOCHO3)OCHHCl→OCH5)①3化学答案第1页共7页

词工(四)夏中等补密李高英语·答案解析water and picking vegetables and fruit.At night,I buriedpick走向重点2023年高考密破考情卷宁夏（四）myself into learning.Seeing them live a happily life,I felt【听力材料】inhappyrelieved.Text 1+L.【解析】第一句的that→which。非限制性定语从句不能M:How was your trip to London?W:It was fantastic.I visited a lot of places.用that引导；which引导非限制性定语从句，修饰前面churches,museums and the royal palaces,的名词village,which在从句中作主语。ar山is门and the weather was fine.Horrible traffie,though.heB2.【解析】第二句的vegetable-→vegetables。vegetable是Text 2可数名词，many修饰名词复数。omod ob w bM:Do you like eating beef,Karen?3.【解析】第三句的go-→went。时间状语是I,ast summer词W:Not really.I hardly eat red meat such as beef,porkvacation'“去年暑假”，表达过去的动作，所以用一般过去单and mutton.eat chicken.时。M:Why?m4.【解析】第三句的here→there。.作者叙述去年暑假在那W:Many studies have tied red meat to cancer and heart里（爷爷奶奶那里）度过了一个月。o1:disease,so I think I'd better avoid such risks.5.【解析】第四句的earlier一→early。very修饰形容词和副Text 3词的原级，且这里没有比较的含义。1munM:Who is the best player in your school football team and6.【解析】第五句的early前加an.early的发音以元音音basketball team?素开头，前面用an。2W:As I know,John is the most popular one in the football7.【解析】第六句删除but。Though引导让步状语从句，team,but Jack plays the best in the team.As for the后面是主句，不能再与but连接。安basketball team,David is second to none.8.【解析】第六句的picking一pick。help sb.do sth,“帮助Text 4某人做某事”；weed,water,pick三个行的省略to的动词不定式作宾语补足语。W:I need to arrive at the ABC Corporation in haf an9.【解析】第七句的into→in。bury oneself in(doing)hour.I'm not sure if I have time to go there on a bus ormaybe I should take a taxi.sth.“埋头做某事”，固定搭配。1O.【解析】第八句的happily-→happy。形容词happy作M:It's just a ten-minute walk.Go along the street and定语，修饰后面的名词life。live a happy life过着幸福turn right.Then you will get there.1baAText 5nor to的生活。M:How much is the parking fee here?书面表达0To Study Liberal Arts or Science?W:It's 1 dollar an hour,sir.If you park your car here lessRecently there is a heated debate in our class onthan 1 hour,we charge you 1 dollar;if you park morewhether to study liberal arts or science.The students'than I hour and less than 2 hours,we charge you 2dollars and so on.opinions vary from person to person.Some students think it is better to learn liberal arts.M:OK.Let me see.I parked my car at 9:00,and it'sFirst of all,it's easier to learn liberal arts.Besides,jobs11:45now.related to liberal arts are not tiring.In contrast,science isText 6W:I was hoping that I'd go to the outdoor shopsdifficult and it takes a lot of pains to learn it.However,others hold the opposite opinions.In theirdowntown today if the weather was fine or evenview,there are a wider range of majors to choose from ifcloudy.But look outside.It's wet everywhere.It'sthey learn science.Additionally,students of science arereally disappointing.,,M:Do you want to go to the Mega Mall with me instead?easier to find a good job than students of arts.Personally,I think what is important is yourI'm going to drive my car there.It's just opened.interest,which decides whether to study liberal arts orW:That sounds good to me.Otherwise I would end upstaying at home doing nothing.science,.姑，再只加稀以水的其，行殖热自的断前感c17B

Several minutes later,a bus stopped and theBbreak rise true people area closedriver(52)noticed them.He decided to helpheavy tower they window happen pupilthem.He asked them to get on the bus.After thebus arrived at the terminal station,he offered themA video gets popular these days.In the video,several people save two school 70 and an old womantowels and hot water.When the rain stopped,aIt 71 after a grandmother picked up herworker sent them home by (53)cargrandchildren from school.On that day,it rainedThree days later,the girl's family came to say2.Their car was trapped(被困)in water.Thethanks to the kind bus driver.People could feel thewater 73 high.They couldn't open the door to getwarmth of the city through the driver's deed.out.70.pupils71.happened72.heavily 73.roseEbreak rise true people area close54.Kathy lives in Shanghai.If she has a picnic nextheavy tower they window happen pupilweek.she'd better choose TuesdayOlivia,the children's mother,got a call from the55.When is World Meteorological Day?On March 23.grandmother and found their location(位置)using online apps.56.Linda is good at painting and wants to doOlivia called the 74 hotel and asked for help.something for the weather.What activity can shetake part in on World Meteorological Day?She also sent messages through her social mediaShe can draw pictures to tell people what toaccount(社交账号).Charlie and Henry,twodo to make a difference.workers in the hotel,made 75 way to the trappedcar with a kitchen knife.74.closest75.their57.How did people know the weather in the past?break rise true people area closeThey watched clouds or felt the wind.heavy tower they window happen pupil58.Please translate the underlined sentence intoCharlie climbed on the car,hoping 76 the car glassChinese.with the kitchen knife.But it didn't work.通过天气预报，人们还可以知道什么时候会发At the same time,Matilda,the children's music生一些恶劣的天气。teacher,came.He swam to the car after seeingOlivia's message.59.What were you doing when it rained in yourHowever,the three people still couldn't breakarea the last time?those car 77.I was sweeping the fl oor when it rainedheavily that noon.76.to break77.windows八.词语运用Abreak rise true people area closeConner and Kane are two students of Grade 8.heavy tower they window happen pupilOne day,60 they were on the bus to school,theAt that time,an owner of a nearby noodledriver stopped the bus suddenly.They saw the busdriver pass out(昏倒).With no adults(成人)near torestaurant brought a big hammer(锤子)andhelped save them.depend 61,the kids knew it was up to themselves.Conner fi rst rose from his seat and made 62 wayWith those 78 help,the two children and theirtoward the driver.He noticed that her face wasgrandmother fi nally got out of the car.Olivia said,really red and she 63 shaking.He quickly realized"To tell the 79,I was so scared.They are ourthat she needed doctors'help right 64heroes!”60.when61.0n62.his78.people's79.truth63.was64.awayAt the same time,Kane picked 65 the radio andsaid,"There's something wrong 66 our bus driver.十.书面表达Seeing what was going on,other children on the每个人都有自己最难忘的一件事。上周六李华和bus were 67 scared that some even started crying.爸爸去游泳，一名男孩不慎掉入泳池，李华爸爸将“Everything will be OK,”Conner said.Then he其及时救出并采取急救措施。假如你是李华，你校organized them to move to the back of the bus 68英文报举办了以“我最难忘的一件事”为主题的征give the driver more fresh air.At last,the driver文活动。请你将周六的所见所闻写一篇英语短文投was saved and everyone was safe.稿。Sometimes it's hard to take proper action under提示：pressure,but trying your best to do something is1.事件发生的时间和地点；always better 69 just being worried.2.事件发生的经过；65.up66.with673.事件发生后你的感想。68.to69.than4

2024届新高三秋季人学摸底考试化学参考答案1.【答案】A【解析】瓷瓶、玉印和玉佩饰的主要成分是硅酸盐，青铜面具的主要成分是铜锡合金，A项符合题意。2.【答案】A【解析】本题考查了分子的极性判断。0F,中0上的孤电子对数为)×(6-1×2)=2，。健电子对数为2，价层电子对数为4,0F2的空间构型为V形，分子中正、负电荷中心不重合，0F2属于极性分子，A项符合题意；CS2中C上的孤电子对数为)×(4-2×2)=0，σ键电子对数为2，价层电子对数为2，CS,的空间构型为直线形，分子中正、负电荷中心重合，CS,属于非极性分子，B项不符合题意；SiCL,中Si上的孤电子对数为)×(4-1×4)=0，σ键电子对数为4，价层电子对数为4，空间构型为正四面体形，分子中正、负电荷中心重合，SC14属于非极性分子，C项不符合题意；02属于非极性分子，D项不符合题意。3.【答案】B【解析】本题考查了实验操作与实验用途对应判断。皂化反应为油脂在碱性条件下的水解反应，A项正确；模拟侯氏制碱法应使用氯化钠饱和溶液，B项错误；碳酸钠饱和溶液可以吸收乙醇，中和乙酸，降低酯的溶解度，C项正确；NaHCO.3可与HCl反应生成NaCl、CO2和水，因此碳酸氢钠饱和溶液可除去CO2中的HCl气体，D项正确。4.【答案】B【解析】本题以氧化石墨烯为载体，考查了物质的导电性、稳定性、键能和原子杂化等。石墨烯变为氧化石墨烯，大π键遭到破坏，故导电性减弱，A项错误；氧化石墨烯中含有碳碳双键和羟基，易被氧化，故抗氧化能力比石墨烯弱，B项正确；氧化石墨烯中C一C键和C一0键均为共价键，C一C键的键长比C一0键K,故C一C键的键能比C一0键小，C项错误：氧化石墨烯中，C原子的杂化方式为sp2和sp,D项错误。5.【答案】C【解析】在碱性条件下氢气被氧化：H2+2OH-2一2H20,A项错误；以铜为电极，铜在阳极发生氧化反应，阳极反应式为Cu-2e一Cu2+,B项错误；亚铁离子还原高锰酸根离子，C项正确；丙烯分子中碳碳双键与溴加成，形成碳溴单键：CH,CH=CH,+Br,→CH,CHBrCH,Br,D项错误。6.【答案】A【解析】前20号元素的原子中，最外层电子排布式为s的原子有氢、锂、钠、钾，元素氢、铍、铝的所在周期序数等于主族序数，结合添加剂的组成可知，X为H元素，Y为0元素，Z为A1元素，R为S元素，W为K元素。0、S、H、A1、K的电负性依次减小，A项正确：K、A1、S、O、H的原子半径依次减小，B项错误；常温下铝不能与水发生置换反应，C项错误；稀硫酸没有强氧化性，D项错误。7.【答案】B【解析】本题考查了实验操作、现象及结论。加人浓溴水后，AL(SO4)3溶液无明显现象，AgNO,溶液中有淡黄色沉淀生成，苯酚溶液中有白色沉淀生成，A项可行；通入S02后，Al,(S0,)3溶液无明显现象，AgNO,溶液出现白色浑浊，苯酚溶液无明显现象，B项不可行；通入足量氨气后，Al2(SO4)3溶液中有白色沉淀生成，AgNO,溶液中先有白色沉淀生成，后沉淀消失，苯酚溶液无明显变化，C项可行；加人酸性KMO4溶液（硫酸酸化）后，A2(S04)3溶液无明显现象，AgNO,溶液中产生白色沉淀，苯酚溶液使紫色褪去，D项可行。化学第1页（共5页）

W:Could I have your keycard please?M:Here it is.I was in room 322.Text 3M:I saw an advertisement in the newspaper about a camera you have on special offer.W:Yes,the Sony Cybershot DSCT 300.It's $50 cheaper now,only $230.M:Great.I'll take it.Text 4M:Would you like to work in a bank?W:No.That would be very boring.I want to be a doctor.And I can help a lot of people.Text 5M:Can't we slow down?I'm tired.W:Slow down?Don't you realize how late we're going to be for the party?Text 6W:How's your school project going,Tim?M:The one about the sky in the evening?OK,I guess.I took some good photos of the moon last week,but then yesterday it was really cloudy.So I couldn't see anything-not even any stars.W:That was a pity.M:Yeah,but at least I've got some pictures to show my teacher.Text 7M:So,Natasha,tell me about your hobbies.Do you like computer games,for example?W:I played a lot of computer games until I was about ten.But I haven't played any for a long time.M:What do you do now?W:I prefer doing exciting things outside.Activities like climbing and snowboarding.You know something that girls may think dangerous.M:Is there anything you haven't tried,but would like to?W:I'd love to go sailing.But my dad says we can't afford it.It needs a lot of money.Text 8M:Amy,my housemate and I are having a house-warming party on Friday night.Would you like to come?W:Sure.Will there be a lot of people there?M:Yeah.We've each invited about 10 people.W:Who are they?M:Some people in our office,my sister,and a few friends from school.You won't be sitting there by yourself.W:What time is it going to start?M:Most people get off work at 6:00 p.m.,so it's going to start about two hours later.W:Should I bring anything?M:We'll have beer,but if you want to bring some juice,that'd be great.W:I could also bring some music if you want.I've got lots of songs on my new iPod.M:That'd be great.Wait for me after work then!I will come on time.Text 9M:Hello,Tourist Information.What can I do for you?W:Hello,I'm phoning about the boat trips on the River Dee.Can you tell me which days they are?M:Sure.They go every Friday and Sunday.英语答案第5页（共6页）

B.“反应器”中温度越高，越有利于制备FeF3C.“系列操作”得到的滤液，可采用分液的方法循环利用D.“灼烧”时通入Ar的主要作用是带走水蒸气防止FeF3水解16.实验室利用环己酮和乙二醇反应可以制备环己酮缩乙二醇，反应原理及实验装置如下图所示：管口A器○0+HO入√OH对甲基苯磺酸分水器苯，△○X8)+o一水反应物和适量的苯旋塞B下列有关说法错误的是A.管口A是冷凝水的进水口B.当观察到分水器中苯层液面高于支管口时，必须打开旋塞B将水放出C.苯的作用是：作反应溶剂，同时与水形成共沸物便于蒸出水0D.若将反应物环己酮改为苯乙酮则和到岛有机产物为第川卷（共56分)二、非选择题：四个大题，每题14分，共计56分，考生根据要求作答17.(14分)高锰酸钾是强氧化剂，用途十分广泛。按要求回答下列问题：I.某化学兴趣小组以绿色的锰酸钾(K2M0)碱性溶液为主要原料在实验室制备Kn0,实验装置（固定和加热装置已省略）如下：单向阀示意图a司浓盐酸弹簧夹止水夹K2MnO浓强碱溶液二氧化锰B(1)仪器b的名称是,侧管a的作用是(2)装置C盛装溶液的成分是(3)单向阀（只允许气体从左流向右）可以起到的作用是(4)装置B中生成KMn0,的离子方程式为化学试卷第5页（共8页）

Human historyHuman history at Biscayne begins more than 10,000 years ago.Scientists say evidence of the area's earliestpeople is mostly underwater now and learn about these people by examining the hills of shells they left behind.Asthe population grew,it divided into separate cultures.The groups began making pottery and created trade networks.These Native Americans are called the Tequesta.The Tequesta depended on the rich food source of the sea tosurvive.They were not centered on farming and had more time than other natives for art and religion.The reefs andrough waters made it difficult for early explorers resulting in more than 50 shipwrecks.Scuba divers today canexplore six of them.Exploring the parkMany visitors to Biscayne National Park choose to explore underwater.Guides lead snorkeling and scubadiving trips.At Boca Chita Key,visitors can explore a lighthouse,a symbol of Biscayne National Park built in the1930s.But visitors to Biscayne National Park probably are not there to see skyscrapers and city lights.The beautyin Biscayne is quiet waters,rustling mangroves.21.What is the feature of the ecosystem in the Biscayne National Park?A.The mixed biological communities.B.The different species of the animals.C.The low-lying islands or reefs.D.The clear and warm waters.22.What can we know from the last two paragraphs?A.Human history dates back to more than 50,000 years ago.B.The Native Americans prefer farming to fishing.C.Scuba divers today are to see skyscrapers and city lights.D.Biscayne is a paradise for the water sports enthusiasts.23.Where is the text most probably taken from?A.A personal diary.B.A travel magazine.C.A geography textbook.D.A book review.心As a reporter,I talk to strangers for a living and love the challenge of getting them to open up.Yet here's aconfession:I've been married for eight happy years,but until six months ago,I could be the stereotypicalinattentive husband.It's not that my wife and I never had pleasant conversations.But more often than I care to admit,I was justgoing through the motions,nodding when I was supposed to..I was the guy who'd defensively snap(厉声说)，“Ofcourse I did!"when my wife would ask,"JB,did you even hear what I just said?"In January,I began to lose my voice repeatedly.Doctors told me I needed surgery,or else my throat would bepermanently damaged.Total silence would be required for the first few weeks of my recovery.Two hours after the surgery,my eyes filled with tears as my two-year-old son stood by me looking puzzledbecause I wouldn't answer his questions.I wanted to talk but couldn't.But before I got home,I had settled into a Zen-like peace about my silence.Soon I noticed another "sideeffect":As my wife talked to me to keep up my spirits,I wasn't just hearing her;I was listening to her.Over the next few weeks,I found myself unwilling to miss a word she said.I began to hear a sweetness in hervoice that I hadn't recalled for long.I found myself understanding her better on topics I'd previously dismissed as“things I just don't get as a guy.”I also realized my toddler(学步的儿童)wasn't just chattering nonstop but that he often had surprisinglythoughtful things to say for his age.Even while walking my dog in the woods near our home,I began hearing pleasant patterns in bird songs.The英语试题第3页（共8页）

1.①n.东道主②v.主办2.①v.出汗②n.汗水3.①v.作弊②n.骗子PART 2I.1.build up my strength2.bringing honour to China3.set a good example4.the master of the football fieldⅡ.1.champion2.injured3.give up4.lose heart5.athletes6.failure(s)PART 3I.1.Compared with to weight lifting2.make a difference3.rather than4.cut out high-fat foodsⅡ.1.isn'the2.No,I didn't3.doesn't it4.isn't it5.Yes,it was;isn't it语言知识应用篇1.a 2.to try3.addicted4.with 5.which 6.has provided

的分压表示的衡常数，分压二气体的体积分数X体系总压)。③在图2基础上画出其他条件相同，向体系加人催化剂时其压强随时间的变化曲线。w生物双照色西方的，R霜震方起始原料结合C0。生产聚碳酸对二甲苯酯可以实现碳成排，毁解日益紧张的能源危机，路线如下：HO-木质HCsH,0Sn-Beta HOCOH纤维素葡萄糖OH CO2OHHOOH高压州CuRu/C催aOH化COOHOHC02Rn-Sn-B催化剂02Al203醋酸CH。醋酸钴VⅧHO VICOOH回答下列问题：M(1)化合物I的分子式为堂(2)分析化合物Ⅱ的结构，预测反应后形成的新物质，参考①的示例，完成下表。序号变化的官能团的名称焙可反应的试剂（物质）反应后形成的新物质反应类型①氧化反应②加成反应烟(3)化合物Ⅲ到化合物V的反应是原子利用率100%的反应，且1molⅢ与1mol化合物a反应得到1molV,则化合物a为(4)已知化合物V的核磁共振氢谱有2组峰，且峰面积之比为2：3，写出化合物V的结构简鸣式：(6)化合物I的芳香族同分异构体中符合下列条件的有种（不含立体异构）。霄①最多能与相同物质的量的Na2CO,反应；②能与2倍物质的量的Na发生放出H,的反应。6)关于M生成Ⅷ的反应的说法中，不正确的有A,反应过程中，有H一O键断裂B反应过程中，有C一O双键和C一O单键形成DC0,属于极性分子，分子中存在由p轨道”肩并肩”形成的π健C该反应为缩聚反应)参照上述信息，写出以丙烯为起始有机原料合成。的路线（无机试剂任选）。