姓名准考证号绝密★启用前炎德·英才·名校联考联合体2024届高三第二次联考化学版权所有翻印必究注意事项：1.答卷前，考生务必将自己的姓名、准考证号填写在答题卡上。2.回答选择题时，选出每小题答案后，用铅笔把答题卡上对应题目的答案标号涂黑。如需改动，用橡皮擦干净后，再选涂其他答案标号。回答非选择题时，将答案写在答题卡上。写在本试卷上无效。3.考试结束后，将本试题卷和答题卡一并交回。可能用到的相对原子质量：H~1C~12N~140~16S~32Cu~64Ag~108一、选择题（本题共14小题，每小题3分，共42分。每小题只有一项符合题目要求）1.“挖掘文物价值，讲好湖南故事”。下列文物的主要成分是合金的是选项ABCD文物大禾人面纹方鼎唐摹兰亭序名称素纱禪衣T形帛画2.化学用语是学化学的专业术语。下列有关叙述正确的是A.异丁醛的结构简式为CH,CH,CH CHOB.相对分子质量为32的氮的氢化物电子式为H:N:HHC.基态锗原子的电子排布式为[Ar]4s24pD.溴乙烷的空间填充模型为3.下列离子方程式符合题意且正确的是A.向酸性KMnO,溶液中滴加甲醛溶液，溶液褪色并产生气泡：2Mn2++5CO2个+11H09鉴m直中13同2MnO+12H++5HCHO-化学试题第1页（共8页）

Va+3=2V3,又a>0,a=3,fx)=2sin(wx+g),又0

9.下列关于人体激素的叙述，错误的是()A.生长激素对肌肉的增生和软骨的形成与钙化有特别重要的作用B.睾酮能增加代谢率，促进男性皮肤增厚和出油，以及促进骨骼生长C.调节女性月经周期的激素是雌激素D.甲状腺激素是胎儿和新生儿脑发育的关键激素10.关于微素的化学本质，下列叙述错误的是()激素化学本质A糖皮质激素类固醇B肾上腺素酪氨酸衍生物C生长激素氨基酸衍生物D促甲状腺激素释放激素蛋白质类A.AB.BC.CD.D11.如图是某二倍体动物体(2N=4)内处于不同分裂时期的细胞图像。下列叙述正确的是()①②③④A.图示过程发生于精巢或卵巢中，细胞④是次级精母细胞或极体B.细胞②③④中均含有同源染色体C.细胞①中可能发生了基因突变D.细胞①中的染色体数：DNA数：染色单体数=8：8：012.如图为反射弧中神经肌肉接点的结构及其生理变化示意图，乙酰胆碱是一种兴奋性神经递质，下列叙述正确的是()一乙酰胆碱一骨骼肌细胞膜A.乙酰胆碱与受体相结合后进入突触后膜，引起后膜去极化B.骨骼肌细胞膜完成电信号→化学信号→电信号的转变C.突触后膜去极化后就能产生动作电位D.乙酰胆碱在突触间隙中以扩散的方式运输13.内环境的各种成分和理化性质保持相对稳定的状态是机体进行正常生命活动的必要条件。下列有关内环境及其稳态的叙述，错误的是()A.静脉注射药物比口服能更快地将药物成分送到组织细胞B.长时间剧烈运动后乳酸能与NaHCO3在肌细胞内发生反应C.人体内环境稳态是依靠神经体液-免疫调节机制来实现的试卷第3页，共7页

8350.6k/sHD HD78成的木偶。分析句子成分可知，空前有谓语动词“is”,空后有谓语动词“operate”,故空处应为连词。分析可知，应为定语从句，先行词为“a folk play”，为抽象的地点名词，在定语从句中充当状语。故填where。65考查非谓语动词。句意：通过木棍和绳子控制，木偶可以生动地做出各种动作。分析句子成分可知，本句的谓语动词为“can do”，且无连词，所以提示词应为非谓语动词，且和主语“puppets”为动宾关系，故用done形式。故填Controlled..66考查副词。句意：皮影戏有自己的特点，但皮影戏的制作程序大多是一样的。分析句子成分可知空处应用副词修饰句子。故填basically。67.考查非谓语动词。根据句意可知play作musicians的后置定语，两者为主谓关系，故用playing。68.考查谓语。句意：皮影戏于2006年被列入国家级非物质文化遗产名录，根据include sth.in the list.可知include和Shadow play是动宾关系，所以应该用被动语态，结合时间状语“20O6”。故填was included.69.考查连词。根据句间逻辑，“not as popular as before”和“remains a highly valuable cultural heritage存在转折关系，故填But。70.考查谓语。句子主语“application of artistic factors”,且在陈述事实，故填guarantees。【短文改错】1.great-一greatly。考查副词，greatly修饰动词change,“很大程度地改变了.”2.whichever→whatever。考查宾语从句引导词，whatever place“任何地方”3.删除an。考查固定搭配4.make→making。考查非谓语动词，making作为结果状语。5.convenient前加more。考查比较结构，much+比较级，convenient的比较级“more convenient'”6.tool→tools。考查名词单复数。7.they。考查代词8.in→for。考查固定搭配have a gift for9.delighted-→delightful。.考查形容词，delightful“令人愉悦的”l0.were→are。此处陈述事实，应用一般现在时，故将were改为are:听力录音稿原文Text 1W:I just spilled red wine on the carpet.Do you have any carpet cleaner?M:No,I just ran out.Get a paper towel and try to get the stain out with water and some salt.Hurry!Text 2M:I need a vacation.I haven't had a day off in eight months.It's about time I did something fun.W:I agree.You've been working hard lately.Why don't we go to Mexico?I can get us a good deal on ahotel.Text3W:Mark,please be quiet.We're in the middle of a test.If you need something,our teaching assistantBrittany is here to help you.M:Sorry,Mrs.Smith.Susie asked to borrow a pen,and I was just telling her I don't have an extra one.Text 4M:If you grab the towels,I'll get the sunglassesW:Okay.Do you have everything else you need?A bathing suit?Your surfboard?高三英语参考答案第6页共8页M:Yes,everything's in the car already.I also packed some sandwiches in case we're hungry later.Text 5W:Lend me a hand,will you?M:Don't tell me you're trying to fix that refrigerator yourself.We need to call in a repairman.W:Do you have any idea what they'll charge?Text 6W:I'd like a ticket to the fair,please.M:OK.This is an entrance ticket only.If you'd like to go to the petting zoo or the horse ride,there willbe an extra fee.W:How much do those cost?M:The petting zoo is $2,and the horse ride is $3.W:I'll buy a ticket to the petting zoo as well,pleaseM:Your total comes to $7.W:Do you take credit cards?M:No,we take cash onlyW:Okay,here you go.Text 7

听力材料听第六段对话，回答第11-12小题。听第一段对话，回答第6小题。(A)11.What festival are they talking about?6.M:The post office is too far.How can we getA.The New Year.there,Kelly?B.Children's Day.W:Well,my father can drive us there.C.The Dragon Boat Festival.听第二段对话，回答第7小题。(C)12.Where is the new supermarket?7.M:This is Bob.What are you doing now,A.Next to the library.Amy?B.In front of the library.W:I'm watching a show about animals on TV.C.Across from the libraryIt is so interesting.g感听力材料听第三段对话，回答第8小题。(A)8.When does the lesson start?听第六段对话，回答第11-12小题。A.At10:30.B.At10:00.C.At9:30.听M:There are so many people in the street,听第四段对话，回答第9小题。Anna.(B)9.Where is the bank?W:Yes.The New Year is coming.They are busyA.Behind the restaurantshopping.What do you want to buy,Bob?B.Next to the restaurant.M:Well,I want to buy some fruit.C.Across from the restaurant.W:A new supermarket is across from thelibrary.Let's go there!g厚听力材料听第七段对话，回答第13-15小题。听第三段对话，回答第8小题。(C)13.Where is the new bookstore?8.M:Come on!We'll be late for the chessA.It is next to the school.lesson!B.It is in front of the school.力W:Take it easy,Jack.It is 9:30.The lesson力C.It is across from the school.starts in one hour.(A)14.What kind of book does Mike want to听第四段对话，回答第9小题。buy?9.W:Excuse me,I'm new here.Can you tellA.About animals.B.About colors.me the way to the bank?C.About sports.M:Yes.Walk along the street,and you canB)15.Why does Mike want to buy it?see it next to a restaurantA.For a test.B.For a birthday.⑧③C.For a report(报告).听力材料B.听对话听第七段对话，回答第13-15小题。听听第五段对话，回答第10小题。W:Hi,Mike.There is a new bookstore acrossB)10.How long does Jane play tennis onfrom our school.How about going there thisSunday?力afternoon?A.For one hour.B.For two hours.M:Sounds great.I just want to buy a bookC.For three hoursW:What kind of book do you want to buy?M:About animals.W:Do you like animals?M:Not really.My sister likes them,so I want tobuy her a book for her birthday.度®W:That's a good idea!C.听短文④请根据所听内容，从每小题所给的三个选项中选出一个最佳答案。短文听两遍。听力材料(A)16.Where is Jason's house?力听第五段对话，回答第10小题。10.M:What do you usually do on Sunday,力A.It is across from a music club.B.It is in front of a police office.Jane?C.It is behind a supermarket.W:I play tennis from 9:00 am to 11:00B)17.When does Jason go to the club?am.In the afternoon I go to the library.A.On Monday.B.On WednesdayC.On Friday(C)18.What can Jason do?③原A.Play the violin.B.Play the guitar.C.Play the drums.6

二全国©0所名校高考模拟金典卷@⊙所名校高考模拟金典卷·数学（四）4.已知抛物线C:y2=2px(p>0)的焦点为F,抛物线C的准线与坐标轴相交于点P点M(3,2),且△MFP的面积为2，若Q是抛物线C上一点，则△FMQ的周长的最(120分钟150分)小值为考生须知：A.4+√2B.4+22C.4+10D.4+2√101.本卷侧重：高考评价体系之综合性5.将一个数字表示成a与10的n次幂相乘的形式，其中1≤a0时，lgx=n十1ga,若一个正整数m的25次方是的融会贯通的综合能力（题8）.18位数，则m=(参考数据：lg2≈0.30,1g3≈0.48)》3.本卷典型情境题：题3、11、22.本卷拔高题：题8、12、16.A.5B.6C.7D.84.本卷测试内容：高考全部范围6.已知AB是⊙O的直径，MA垂直于⊙O所在的面，C是圆周上不同于A,B两点的任意一点，若AB=2,MA=BC,则四面体MABC的体积的最大值为、选择题：本题共8小题，每小题5分，共40分.在每小题给出的四个选项中，只有项是符合题目要求的：A③3B339C439D83271.已知复数之(2+i)=1一3i,则之的共轭复数乏=7.在一个单位方格的四边形中，若有两条边染了颜色α，另两条边分别染了A异于a色的另两种不同的颜色，则称该单位方格是“a色主导”的.如图，现C.要对这10条线段染色，每条线段染为红、黄、蓝三色之一，使得上红色主D-号+导，右黄色主导，下蓝色主导，这样的染色方式种数为封2已知集合A=y=V3t,B=x∈Z引吕∈Z,且EANB,.则e的所有取值A.72B.137C.171D.1938.【拔高题】已知函数f(.x)=x2·e-1一2lnx-(a+3)x,且对于Vx∈(0，十∞)，的和为f(x)≥0，则实数a的最大值为A.-20B.-17C.-13D.5A.-3B.-2C.-1D.03.小李最近一个星期的总开支如图1所示，他这个星期的食品开支如图2所示，则二、选择题：本题共4小题，每小题5分，共20分.在每小题给出的选项中，有多项符合其他5%120开支/元题目要求.全部选对的得5分，部分选对的得2分，有选错的得0分1009.已知向量a=(7,3),b=(m十1，一2m),m∈R,则下列说法正确的是食品开支8030%线A.若a⊥b,则m=一3B若alb,则a+1=2V2940日常开支20%20通讯开支5%C若a/b.则m=是D.若a∥b,则a+b1=383娱乐开支10%鸡蛋牛奶肉类蔬菜其他食品种类10.已知公差为d的等差数列{am}的前n项和为S,n,若a39十Ss=0,则下列说法正确图1图2A.小李这个星期的食品开支为270元的是B.小李这个星期的牛奶开支占总开支的5%A.当d=3时，an=3n-27B.当S14=42时，d=一3C.小李在食品开支中除了鸡蛋、牛奶、肉类、蔬菜的其他开支占他这个星期的总开C.当Sn有最小值时，S6S2支的5%11.定义新运算“☒”，使其具有下列性质：①对Hm,n∈R,m⑧m=n⑧m;②对Hm∈R,D.小李这个星期的娱乐开支占总开支的比例最小m&0=;③对Hm,n,k∈R,(m☒)☒k=k&(mm)+(m☒k)+(n&k)-2k.若函数学（四）第1页（共8页）【24新高考·JD·数学-N】数学（四）第2页（共8页）【24新高考·JD·数学-N】

Text 8M:But it was not until 1908 that the tea bagW:Hi,Alan,I haven't seen you for a few weeks.became popular.A New York businessman ofAre you busy with the basketball training?tea was looking for a less expensive way toM:No,Linda.Final exams are coming.I spendpackage tea for his customers and beganmost of my time in the library (11)packaging his tea samples in little bags made ofW:Well,the term is almost over nowsilk.(16)W:Oh,I see.The tea bag is a modern convenience.M:Yeah.I'd like to travel around the country inMy grandfather loves tea a lot.He drinks teathe coming vacation.But I am on a budgetevery day after meals.W:Have you thought about camping?It hasM:Me too.There isn't much tea left in my house.become one of the most popular choices forLet's go and buy some.(17)young people these days.W:Sure.You can rent the equipment you need.It's听第10段材料，回答第18至20题。418-20CBBmuch cheaper than buying it or staying at a18.What is editors'task on Monday?hotel.A.To write headlines.M:Good idea!We can drive until we find a niceB.To check the language.spot and just camp wherever we like.(12)C.To decide what stories to write.W:Well,not exactly.It's usually not allowed19.How long does it take to make an edition ofunless you camp in designated areas.There areTeens?many national parks owning campgroundsA.A whole day.B.A week.C.Half a montharound the country.20.What is the speaker mainly talking about?M:I see!Here comes my bus.(13)I'll talk to youA.The current situation of newspapers.about this again and get all the details.B.The process of making a newspaper.C.The importance of reading newspapers.Text 10听第9段材料，回答第14至17题。Even though more people choose digital reading14-15BAnowadays,some still would like to read newspapersbefore breakfast.It has become an important part14.What are the speakers mainly talking about?of their daily life.But do you know how aA.A booknewspaper is made?(20)B.An invention.There are many steps to make a newspaper.TakeC.A type of tea.Teens for example.On Monday,editors and15.When was the tea bag invented?reporters hold a meeting to decide on the stories forA.In1901.the week's paper.(18)On Tuesday and Wednesday,B.In1908.C.In1918reporters write news stories.Cartoonists drawcartoons and photographers take pictures to matchthe stories.16-17BAForeign editors check the language.On Thursday,page designers put the stories,16.What material did the New Yorkcartoons and pictures on the pages.Editors readthrough the stories to find mistakes and writebusinessman use to package tea?headlines and captions.A.Paper.B.Silk.C.Cloth.Friday is a busy day.Page designers print the17.What are the speakers going to do next?page drafts.Editors read pages and check themA.Buy some tea.again.At night,Teens comes out in the printingB.Have tea together.house.C.Visit David's grandfather.Teens is a weekly newspaper.(19)Dailynewspapers have all the same steps,but they need8to do them all in a day instead of a week.Text 9第第一节W:What are you doing,David?M:I'm reading a book about tea.Do you know部how the tea bag was invented?(B)21.What is the aim of the first book?W:I have no idea.Tell me pleaseA.To show how to be a journalist.M:It is said that in 1901 two women in the USB.To teach teens how to deal with anxiety.invented a tea-leaf holder.(15)Although it wasC.To teach teens how to read others'thoughtsmade of cloth instead of paper,it looked quite读D.To show how to balance schoolwork andsimilar to the tea bags we know today.W:That sounds interesting.social life.

4.I'll have steak,French fries,and chocolate icePart◎要点归纳1cream for dessert(甜点).worth adj.“值得…的；有…价值的5.-What can I do for you,sir?sth.+be+worth+名词或代词表示“（某物一I'd like a meat pie and a cup of lemon(柠值得、有价值、值（多少钱）”檬)tea."It is (well)worth doing sth.sth.be (well)+worth+doing'”表示“（非常）值得做某事g度回例句Ⅱ.根据汉语意思完成英语句子，每空一词。The science museum is worth a visit.这个科学博物馆值得参观。1.请坐下吧！让我们谈谈。The computer costs me a lot of money,but it'sHaveaseatplease!Let's talk.worth it.2.这顿饭的主菜是牛排。这台电脑花了我很多钱，但它物有所值。The main course of the meal is steak.The watch is worth about 800 yuan.3.你可以通过电话来订餐。这块手表大约值800元。You can order a meal byphoneIt is worth reading Journey to the West.=Journey to the West is worth reading.《西游记》值得阅读。4.别担心。我们将在二十分钟内完成这项工作。©同步练Don't worry.We will finish the work in(A)1.I'm not surethe book is worthtwenty minutesor not.5.你能帮我把药给琳达送过去吗？A.whether;readingCan you help me send the medicine toB.if;readLinda?C.that;readingD.whether;to readg摩Ⅲ.按要求改写句子，每空一词。l.Mrs.Green cooked fish for dinner.(对画线部分©要点归纳2提问)What didMrs.Green cook for dinner?both…and两个都；既又”，用宇2.We will send the food to you in thirty minutes.连接两个并列的句子成分。当它连接两个并列(对画线部分提问)主语时，谓语动词用复数形式。How soon will you send the food to me?3.The roast chicken is25yuan.(对画线部分提问)How much is the roast chicken?4.I ordered something else for drink.(改为一般疑回例句问句)*At the party,they both sang and danced.Didyou order anything else for drink?在聚会上，他们又唱又跳。5.Wang Lei can't speak English.I think..(合并为Both my big sister and little brother like eating一个句子)Beijing Roast Duck.I don'tthinkWang Lei can speak我的姐姐和弟弟都喜欢吃北京烤鸭。English.6

00:16令38语文答案2(1).pdf兼顾。(3)论证思路方面：因果分析的逻辑思路。(3分。每点1分)语文参考答案第1页【译文】唐太宗刚刚即位，就在正殿左侧设置了弘文馆，精心挑选讲求礼乐教化的儒生，让他们保留现任的官职并兼任弘文馆学士，供给他们五品官员才能享用的精美的膳食，按日轮换着在夜间值班，太宗在上朝听政的间隙时间，就把他们引进内殿，和他们讨论古代典籍，商议谋划政事，有时到半夜才停歇。贞观二年，唐太宗下令停止尊崇周公为先圣，在国立学校里建立孔子庙堂，取法过去的规定，尊崇孔子为先圣，颜子为先师，（庙堂供台）两边祭祀用的俎豆、千戚等礼具和乐舞之具，在当时也开始齐备了。这一年，唐太宗还招纳大批天下儒士，赏赐给他们布帛，供给车马食宿，下令他们都集聚到京师。这些儒生大都被破格提拔，在朝廷上任官的很多。精通一大经以上的经书的太学生，都得到了官职。在这之后，国立学校增益学舍四百多间，国子学、太学、四门学、广文馆也增加了学员。吐蕃和高昌、高丽、新罗等外族首领，也派子弟到长安求学。于是国立学校之内，带着书箱和登上讲席的，几乎有上万人，如此大兴儒学，在古代还不曾有过。贞观四年，唐太宗认为经书距离古代圣人的时代已经很远了，出现了很多文字讹误，就下令前中书侍郎颜师古在秘书省考订《五经》。等到考订完毕之后，又下令尚书左仆射房玄龄召集许多儒生再次详细讨论。当时儒生们学并接受师传旧说，而这些旧说错乱讹误相传已久，他们都不同意颜师古的考订，一时之间各种异说蜂起。于是颜师古引用晋、宋以来古本，针对他们提出的疑义给予明白清晰的回答，引经据典详细而明确，都出乎他们意料，这些儒生无不叹服。唐太宗对颜师古也大加称赞了好久，并将他考订的经书领行天下，让读书人都来学。（后来）唐太宗又因为经术师承不同，解释各异，且章句繁杂，下令颜师古和国子祭酒孔颖达等大儒，撰写《五经》的疏义，名为《五经正义》，交付国子监作教材使用。贞观二十一年，唐太宗又下诏说：“左丘明、卜子夏…二十一人，从现在起太学里凡举行祭祀之典时，可使他们配享孔子庙堂。”太宗就是像这样尊儒重道。唐太宗曾对中书令岑文本说：“人虽然秉有一定的天性，但必须博学才能有所成就。就好比蜃的本性含有水，要见到月光才能吐水；木的本性含有火，但要燧石敲打才能发火。人的本性含有灵气，可是要通过学才能美好完善。所以历史上有苏秦刺股读书，董仲舒放下帷帐讲学的美谈。不勤奋于道艺，功名是不会树立的。”岑文本回答说：“人的本性都很相近，情趣却有所差别，必须用学来修养情趣，使本性完善。《礼记》说：‘玉石不经雕琢就不会成为器具，人不学就不会懂得道理。’所以古人勤于学，被称为是一种美好品德。”15.D(这四句是诗人直接陈述自己对“贵者”和“贱者”的看法。他一反世俗之见，将“贵者”视若尘埃，“贱者”看得重若千钧，进一步抒发了自己愤激的感情。)16.①表达了对荆轲脾睨四海、蔑视豪门势族的英雄气概的赞美与敬仰之情。②借荆轲表现了诗人对当时豪门势族的蔑视。③对自己不公遭遇的愤懑不。他虽才华出众，但英雄无用武之地，壮志难酬。（每点2分，共6分。如有其他答案，言之有理即可得分）【赏析】这首诗赞颂荆轲睥睨四海，蔑视豪门势族的英雄气概。荆轲刺秦王是为了除暴安民，但是刺客的行为是并不足取的，只是他的事迹确有感人之处。左思赞颂荆轲，固然是佩服荆轲的为人，而更主要的是借以咏怀，表示对豪门势族的藐视。开头四句写荆轲在燕国的都市里饮酒，酒兴正浓，气概不凡。高渐离击筑，荆轲高歌相和，甚至激动得流下眼泪，好像身边没有别的人似的。这里写的只是荆轲生活的一个片断。但是已足以表现他的思想性格和为人，已使人感到不同凡响。“虽无壮士节，与世亦殊伦”是对荆轲的评价。语文参考答案第2页前句是贬，后句是褒。一贬一褒，贬中有褒。褒是主要的，而贬只是指出其不足。这个不足是与壮士鲁仲连比较而言。鲁仲连退秦兵成功了，荆轲刺秦王却失败了，所以说“无壮士节”。但是，在句首冠以连词“虽”字，是表示退一步说，其正面意思在“与世亦殊伦”。因此可见左思对荆轲的为人还是肯定的。这个意思在下面句子中就更明显了。“高眄邈四海，豪右何足陈？”是写荆轲的英雄气概。他高视不凡，四海尚且以为小，那豪门势族岂值得一提。左思满怀壮志，希望能施展自己的才能，为国家出力。但是，在门阀统治的压抑下，英雄无用武之地，仕途蹭蹬，壮志难酬，他对自己的不公遭遇充满了愤懑不的感情，故假借荆轲表现了他对豪门势族的蔑视。“贵者虽自贵”四句，是诗人直接陈述自己对“贵者”和“贱者”的看法。他一反世俗之见，将“贵业”洞北小“跳业”玉但玉些工出洲止名出了白了批出咸生户用经问泄兴兰法【如女阿