绝密★启用前2023届高三分科模拟检测卷（四）·化学注意事项：[满分100分，用时90分钟]7工答题前，考生务必将自已的学校，姓名、班级，准考证号填写在答题卡上相应的位置2.全部答案在答题卡上完成，答在本试卷上无效。3、回答选择题时，选出每小题答案后，用2B铅笔把答题卡上对应颗目的答案标号涂黑。如需政动，用橡皮擦干净后，再选涂其他答案标号。回答非选择题时，将答案用0.5毫米及以上黑色笔迹签字笔写在答题卡上。4.考试结束后，将本试题和答题卡一并交回。w和可能用到的相对原子质量：H1C12N14016Na23S32C135.5Mo96一、选择题：本题共15小题，每小题3分，共45分。每小题只有一个选项符合题月要求。1.化学与生活、科技、社会发展息息相关。下列说法不正确的是B半料种G为单品可以作为光电转换材料，用于太用能范了B.现代科技拍到的氢键“照片”直观地证实水分子间氢原子与氧原子间形成的化学头C,锅炉上的水垢，通常先用碳酸钠溶液进行预处理，形成疏松物质后再用酸除去√D.新冠病毒奥密克戎变异株传播性更强，其成分含有蛋白质的2.实验原理与装置能达到实验目的的是杯冷水烂NHa粗碘Feso,食盐水溶液浸泡过溶有CO2的的铁钉饱和食盐水丙荣A.利用装置甲提纯粗碘B利用装置乙验证铁钉能否发生桥氢腐蚀常C,利用装置丙蒸干溶液获得FeSO4·7H2OD,利用装置丁制备NaHCO?3.NA为阿伏加德罗常数的值。下列说法错误的是A.2.0gH218与D,160的混合物中含有的中子数为NAB.3 mol NO2与H20完全反应时转移电子数目为2NA3版+加=22+0C.1mo1NH,F中含有的共价键数为4NH-H↑2horD.标准状况下2.24LC1,溶于水时，所得溶液年含氯微粒总刻0.2NA4.异甘草素具有抗肿瘤、抗病毒等功效，结构简式如图所示。下列说法错误的是0MtH0己+H0蒙A可与FeC13溶液发生显色反应-1B、分子中所有碳原子可能共面1十0C苯环上氢原子发生氯代时，一氯代物有5种D.异甘草素完全加氢后所得分子中含6个手性碳原子5,三种前四周期主族元素XY,乙形成的一种化合物具有盒效的储氢性能，其氢含量高达7.84%，释氢时的原理为Z(YX4)2一ZX2十2Y+3X2。下列说法错误助是A化合物Z(YX,)2中的Y不满足8电子稳定结构B.化合物Z(YX2中含有离子键、共价键，配位键C.同周期中第一电离能小于Y的元素只有1种D.YX4为正四面体结构【名校之约系列2023届高三分科模拟检测卷（四）·化学第1页（共6页）WS】

A销误w成时，烧杯甲为正极区，烧杯乙为负极区，烧参考答案及解析林乙中宏生氧化反应B正确6点时：电压为0，电流为10-4,7,反应达到指状态，C正确c点时，衡左移，正极,曲线Ⅱ对应的电离衡常数为10，由题中的电极反应为6十2e一2，D正确。信息，NH,·H,O碱性大于MOH,所以曲线I对应1Q.B【解析】本题考查条件控制，实验操作，离子方程式的是滴定NH,·H,0溶液的曲线，A正确H点对应c(NH)书写，氧化还原反应等。升高瀛度可加快反应速率，的：CNH,H,0为10-，温度不变，电离衡常数放适当升高温度，可提离“氧化沉铁”的速率，A正确)不变，c(OH)=103,pH=11,B正确6、e点溶液对“氧化沉钻”的条件为弱酸性条件，离子方程式应为应的pH分别为9,26,8，滴定终点之前溶液碱性越强，CIO-+2Co+5HQ2Co(OH)4H+水的电离程度越小，由已知，NH·HO碱性大于B错误，“滤液”中溶质主要为N:S0,可回收利用、MOH,b,e点溶液中水的电离程度bC,而在碱性条件下KMnO:之Cl,,可知物(2)三角双维形(1分)质的氧化性与pH有关，故D正确。(3)HF(1分)HS分子间只存在范德华力，HF分12,B【解析】过程I为加成反应，根据元素守恒，过程Ⅱ子间除存在范德华力还存在分子间氢健，故HF的沸中有HO生成，A正确，M分子中含有碳碳双键和醛点高(2分)基，能使酸性高锰酸仰溶液褪色，而对二甲苯也可以(4)d(2分)与酸性高锰酸钾溶液反应，B错误；根据乙烯的面形(5)12(1分)氧原子(1分)分子结构分析可知，丙烯醛分子中所有原子可能共3/8×28+16×16×10(2分).面，C正确；M分子的不饱和度为3，而芳香族化合物4的不饱和度至少为4，所以M不可能具有芳香族同分【解析】本题综合考查了价电子排布图、洪特规则特异构体，D正确。比梦处第示考中(例、分子空间结构、氢键、杂化方式、晶胞构成及有关13.AC【解析】本题以利用电解的方法将白磷转化为二,计算等内容。氰基磷负离子的锂盐L汇P(CN)门为戴载体，考查电极(1)砷为第四周期VA族元素，同族上方相邻元素为反应，离子交换膜、电极区质量变化、电解总反应等。磷元素，由信息可知，梯与砷同族相邻，放梯位于第五HCN为弱酸，所以阴极电极反应为2HCN十2eˉ周期，基态铆原子价电子排布式为5s25p,轨道表示2CN~十Hz↑，A错误，分析装餐图，阴极产生的CNT5s5p通过隔膜到阳极室，既能衡阴极室电荷：又可提高式为四不：虽然梯的5p轨道处于半充满状态，1i[P(N):]的产量，B正确，电解生成1molH:时，但铆位于元素周期表中金属与非金属分界线的下方，阴极区减少的质量为2 mol HCN的质量，为54g,C属于金属元素，而其同周期右侧相邻元素位于金属与箱换，电解的总反应方程式为P十4HCN十L,iCN非金属分界线的上方，属于非金属元素，故梯的第一电离能小于同周期右侧相邻元素的第一电离能。题电1，P(CN:]+2H↑，D正确.(2)由于SbF,属于具有立体结构的非极性分子，则其AD【解析】本题以一种过氧纪酸盐离子液体催化烯空间结构具有高度对称性，故5个F原子中的3个形经环氧化为载体，考查催化剂、化合价、溶液构成、物成正三角形，Sb原子位于正三角形的中心，上下各有质结构和性质等，离子」转化为离子2的过程不是1个与其等距离的F原子，为三角双熊形。直接猫化婚烃环氧化，A错误，铌的化合价一直不变·(3)由于H,S分子间只存在范德华力，而HF分于间B正确，盐溶液中一定祥在阴离子和阳离子，C正确，除存在范德华力外，还存在分予间氢健，故F沸离子1中不存在过氧辘，D错讽，点15.C【解析】本题以0.名mol·1,的盐酸分别滴定(4)SH,SbR的阴离子为SbF7,中心原子为Sb原子，20mL.0.2mol·1,-的氨水和M0H碱溶液为截体，考查图像分析、滴定过程分析，水的电离程度，离子浓其价层电子对数目为号×5一1X6+)+6=6,即杂度等。分析图像，曲线T对应的电离衡常数为化轨道数目为6，则杂化方式推断合理的是Pd,

二填空题：共4个小题，共58分。上NHC3和15.(16分)随着原子序数递增，八种短周期元素（用字母xy等表示）原子半Ca(OH)径的相对大小，最高正价或最低负价的变化如图所示。回答下列问题：H7、Ht.NvNV(1)实验室制备氨气的0原子序数NAoH+0V匹A(1)h在元素周期表中的位置为(2)x与e形成的化合物的电子式为NaHA的进气口为(2)若观察到装置B中(3)f的最高价氧化物对应的水化物反应的化学方程式是VIIA质是。ZNavHt Al03午24WAA,(4)元素d与g的氢化物组成和结构相似，相同条件下二者沸点较高的,0(3)为防止环境污染，。是(填化学式)，原因是气的是(5)z、d、©、f这四种元素分别形成的简单离子中离子半径最小的是填离子符号)。02①(6)化合物x2d2所含化学键为(填共价键类型)。Ⅱ.氨气与二氧化氮的(?)元素的原子得电子能力越强，则元素非金属性越强。下列事实不能(4)铜和浓硝酸产生」说明h的非金属性比g的非金属性强的是(填标号)。(5)将I中收集到的】A将h的单质通人g的气态氢化物形成的溶液中，有淡黄色沉淀催化剂，充入NO产生B.g与Fe化合时产物中Fe为+2价，h与Fe化合时产物中Fe为+3价在一定温度下按C.用h的氢化物可以制出g的氢化物X中的气体缓慢；p.化合物gh中，h的化合价为一1价16.(18分)氮氧化物(NO)是大气污染物之一，工业上在一定温度和催化(6)若有NO2和NH剂条件下用NH将NO,还原成N。某同学在实验室中对NH与中，经氧化得到的NO2反应进行了探究。回答下列问题：NO与NH的I,氨气的制备17.(16分)氮氧化物(0某化学实验小组同学利用以下装置制备氨气，并探究氨气的性质（部分(1D以上污染物造团仪器已略去)。种即可)。化学试题第5页（共8页）

要生用人打名师导学·选择性考试第一轮总复·生物(3)兴奋在突触处传递比在神经纤维上的选项实验操作预期结果传递速度要慢。原因是兴奋由突触前膜传至剪断背根中央处，刺激背根向中段蛙后突触后膜，需要经历化学信号转换，如递质的分别电刺激背根向肢收缩；刺激背根外周释放、扩散以及对突触后膜作用的过程。中段、外周段段不发生反应【易错提醒】剪断腹根中央处，刺激腹根向中段蛙后(1)静息电位不等于零电位B分别电刺激腹根向肢收缩；刺激腹根外周静息电位时，由于K+外流，使得膜外的阳中段、外周段段不发生反应离子浓度多于阴离子浓度，而膜内的阴离子浓剪断脊神经，分别蛙后肢均不收缩度多于阳离子，表现为外正内负，不是零电位。电刺激背根、腹根(2)神经纤维上兴奋的传导方向：在体内剪断背根、腹根中央蛙后肢收缩与离体情况不同处，电刺激脊神经①离体时，刺激神经纤维上某处，兴奋可【重点归纳】判断反射弧中受损部位的沿神经纤维双向传导。方法②在生物体内，神经纤维上的兴奋只能来(1)判断传出神经是否受损：将电流计连自感受器，并沿反射弧单向传导至效应器，所接在神经纤维上，当神经纤维受到刺激时，若以在生物体内，兴奋在神经纤维上是单向传电流计不发生偏转说明受损部位是神经纤维；导的。若电流计发生偏转说明受损的部位可能是骨例3将青蛙脑破坏保留脊髓，在脊柱下骼肌或突触。部打开脊椎骨，剥离出脊髓一侧的一对脊神经(2)判断骨骼肌是否受损：刺激骨骼肌，若根（包含背根、腹根和由背根腹根合并成的脊骨骼肌不收缩，说明受损的部位是骨骼肌神经，见下图)。已知分别电刺激背根、腹根、(3)判断突触是否受损：刺激骨骼肌，若骨脊神经均可引起蛙同侧后肢发生收缩。若利骼肌收缩，说明骨骼肌正常；然后刺激神经，若用上述实验材料设计实验，以验证背根具有传电流计偏转，但骨骼肌不收缩，则说明受损的入功能，腹根具有传出功能，实验操作和预期部位是突触。结果都正确的一组是背根脊神经脊髓腹根246

解析：CH3CH2OH与CH3COOH反应生成CH3 COOCH2CH3,发生酯化反应，也属于取代反应，CH3CH一CH2与Br2在光照条件下反应生成CH2BCH-CH2,属于取代反应，A项不符合题意；CH=CH2与H2O在催化剂、加热、加压条件下反应生成CH3CH2OH,属于加成反应，CH一CH2在催化剂条件下生成王CH2一CH2m,属于聚合（加聚）反应，B项符合题意；CH2一CH2与HC1在催化剂、加热条件下反应生成CH3CHCI,属于加成反应，CH3CH一CH2与H2在催化剂、加热条件下反应生成CH3CH2CH3,属于加成反应，C项不符合题意；CH3CHOH与氧气在铜或银作催化剂、加热条件下反应生成CH3CHO和HO,属于氧化反应，CH3CHO与氧气或酸性高锰酸钾溶液在加热条件下反应生成CH3COOH和H2O,属于氧化反应，D项不符合题意。答案：B

组别①②①DNA分子，可能引起,攻击使其活性下降引起细胞衰老葡萄糖溶液面萄糖溶液+葡萄糖溶液十葡萄糖溶液(2)乳酸萄糖溶液(填“能”或“不能”)作为神经元的能源物质，原因是实验处理无蓝水酵母菌酵母汁A溶液B溶液_。抑制MCT可降低神经元损伤，依据是实验结果+(3)某兴趣小组发现，人体运动强度与O,的消耗量和血液中乳酸含量也有密切关系（如图2）。注“+”表示有乙醇生成，“-”表示无乙醇生成A级冲液提供酶促反应的适宜pH,以确保酶的活性①人体无氧呼吸时葡萄糖中的能量去向有②在三种不同的运动强度下，请判断肌肉细胞中C0,的产生量与O,的消耗量的关系，并B可选用溴麝香草酚蓝水溶液检测有无乙醇的生成说明理由C.第⑥组的实验处理为葡萄糖溶液+A溶液+B溶液D.①②③组对比可验证利用无细胞的醇母汁可以进行乙醇发酵12.(14分)某学小组用相关装置测定酵母菌细胞呼吸的方式，相关数据测定结果如图所示。请回答下列问题10.某实验小组欲利用核桃幼苗研究氮素形态对根系呼吸速率的影响，在其他条件相同且适宜的(1)在200~300s时间段内，酵母菌的细胞呼吸方式为百精含量/(mgL)情况下，通过调整营养液中NH-N与NO-N的比例，共设置A(100%:0%)、B(75%,此时间段最终产生的物质除酒精25%)、C(50%:50%)、D(25%:75%)、E(0%:100%)5个氮素形态，连续每月测定并统计外，还有一02含量一次。进行素形态处理前对栽培基质浇灌大量清水，最后测定实验结果如图所示。下列(2)在0~100s时间段内，装置中酵母菌(填“能”或酒精含量/52述正确的是“不能”)发生[H与O2结合生成水，判断依据是4。30s后，醇母菌细胞呼吸产生的C0,与酒精的物资的量0350时间(填“相等”或“不相等”)，原因是3)将酵母菌置于含有葡萄糖溶液的密闭的锥形瓶中，测得C0的释放量比O的吸收量大1A根细胞进行无氧呼吸消耗水的场所是细胞质基质倍，则有氧呼吸消耗的葡萄糖的量与无氧呼吸消耗的葡萄糖的量的比值为(坑B,只能用单位时间内CO,的释放量表示呼吸速率标号)。C.随着处理时间的延长，核桃幼苗根系呼吸速率逐渐升高A.1:4B.1:3C.1:2D.1:1D.单独施用NH-N的核桃幼苗根系呼吸速率高于单独施用NO-N的(4)某生物兴趣小组在做酵母菌发酵实验时，先通氧，后隔氧，发现产生的酒精量比一直隔氧情况下产生的酒精量多，主要原因是13.(13分)蓝莓果实中富含花色素苷、维生素等，具有抗氧化、抑菌和抑制肿瘤生长等作用。某研究小组为研究蓝莓枝条不同部位的耐低温能力，利用人工模拟低温胁迫的方法得到如下实验第Ⅱ卷（非选择题共40分）结果（注：总呼吸强度用耗氧速率表示）。请回答下列问题二、非选择题（本大题共3小题，共40分。）(1)O2在细胞呼吸中的作用是11.(13分)图1为两种细胞代谢过程的示意图。转运到神经元的乳酸过多会导致其损伤。研究与生物体外燃烧相比，有氧呼吸具有不同的特点，表现在发现，Rhb蛋白能促进丙酮酸进人线粒体氧化分解供能。请回答下列问题：窗白元和↑(写出两点)凤履，-两南煎分一收质细胞(2)该实验必须在黑暗条件下进行，原因是温设m据图可知，1年生茎尖较1年生茎基对低温胁口乳酸含量迫更加敏感，判断依据是酚丽神经元(3)随着温度的降低，蓝莓1年生枝条尖端（茎尖）、1年生枝条基端（茎基）和2年生枝条（茎运动强亚的呼吸速率都会下降，原因是图21)据图1可知，在线粒体内氧化分解的物质有图中的自由基会攻击·12·【24·G3ZC·生物（六）-R-必考-SX)

下列问题：1)仪器。的名称是牛植笔(2)在环戊酮的制备和纯化阶段，均使用了温度计，但是两次使用温度计的目的不同，制备阶段使用温度计是为龙蜂花阶段使用温度计是为了使红成飘怎礼®)实验中Ba(OD,的加人除了可以加快反应速率外，另一个作用是叹，2礼入C小，么位办乙日(40粗产品中加入碳酸钾图体的目的是减2.或同中心多，每利3乡尾)心站-一乙孩(5)收集128一131℃的馏分，得到环戊酮8.4g,则该反应的产率为(6)保证反应产率的关健因素在于控制反应遇度，反应温度控制在285~295℃，若温度过低，则链若温度过高，则乙二被证斋4儿18.(13分)将二氧化碳转化为高附加值产品是改善温室效应的有效措施，二氧化碳催化加氢制取甲醇的主要反应如下：反应I:CO2(g)+H(g)C0(g)+H2O(g)△H1=+41.21kJ/mol反应1：CO2(g)+3H2(g)=CH,OH(g)+H2O(g)△H2=-49.16kJ/mol反应I:CO(g)+2H(g)=CH,OH(g)☑%乙o·-h.回答下列问题：②-0a.1(1)“反应Ⅲ”的△H=kJ/mol.(②)依据化学反应的特征分析，获得较高甲醇衡产量的反应条件是C(填标号)。A.高温高压B.高温低压C.低温高压凡低温低压(3)已知250℃和5.0MPa下，在进料气体H,与C0,的体积之比为3：1时，C02衡转化率为n(生成的CHOH)30%,甲醇选择性为70%【甲醇选择性X(CH3OH)=×100%】。n(消耗的C02)①氢气的衡转化率α(H2)=②“反应I”的衡常数K。x写出计算式即可)。(4)向恒压(3.0MPa)密闭容器币通人反应物【V(CO2):V(H2)=1：2】。二氧化碳加氢制甲醇的速率方程可表示为：0=·p”(CO2)·p”(H2),其中飞为速率常数，各物质起始分压的指数为各物质的反应级数。实验表明，速率常数与反应级数均受反应温度的影响。用Ni,G?作催化剂，将反应温度由169℃升高到223℃，两温度下起始反应速率之比℃=2，若C0,反应级数mc-2,U1690m169℃2反应级数不变，则速率常数之比心一。0(5)研究证实，CO2在酸性水溶液中电解可生成甲醇，则生成甲醇的电极反应式为(6)在催化剂Na一FeO/HZSM-5的作用下，二氧化碳可以加氢制得汽油，变化过程如图所示，则二氧化碳生成汽油中CH。的化学方程式为D)C0,→C0→(CH2)CH)→CFe,OFe.C.Acid4出Na-FeO/HZSM-578%Gasoline(汽油)2023届高三高考模拟测试化学试卷第5页（共6页）CgMig

全国100所名枝最新高考模拟示范卷入全国100所名校最新高考横拟示猫卷人Cl(aq)+H2O(D)-H+(ag)+Cl-(aq)+HClO(aq)K=4.2X10-②Cl2(aq)+C1-(aq)一C15K2=0.19100.0099.95锌的回收率③HC10(aq)一H+(aq)+C10(aq)K,=3.2×10-41下列说法错误的是99.8065Aa点溶液中存在：c(H+)>c(C1)>c(Cl)>c(CIO)除铜效果43B.b点溶液中存在：c(HCIO)+c(CIO)+c(Na+)=c(CI)+c(Cl)99.6599.60299.55C.在HC1溶液中，随着盐酸浓度的增大，n(C0'n(HCO)减小99.50g0100110120130140(NH),S加人量/%D.由上述实验得出C1对C的溶解存在较大的抑制作用①当NH)2S的加入量>100%时，锌的最终回收率下降的原因是(请结合题序23456789101112131415c[Zn(NH)答案离子方程式回答).已知：ZA0NH)了的Ke22XN)-29X10.②“深度除铜”时，(NH4)2S较为合理的加入量约为120%，理由是第Ⅱ卷（非选择题共55分）(⑤)“电解”时，使用惰性电极，阴极存在竞争反应。该竞争反应的电极反应式为二、非选择题：本题共4小题，共55分。16.(14分)锌是一种重要的金属，锌及其化合物被广泛应用于汽车、建筑、船舶、电池17.(14分)四乙酸硅[Si(CHC00)4]是重要的化工产碱石灰等行业。现某科研小组以固体废锌催化剂（主要成分为ZnO及少量FezO、CuO、品，某实验小组用SCL和(CHCO)O合成四乙酸MnO、SiO2)为原料制备锌的工艺流程如图所示：硅，装置如图所示（部分夹持装置略），已知：CH,C0)20过量NH-NH,CI溶液①SCL4是无色油状液体，易挥发，易水解；H,02溶液有鼓座②乙酸酐[(CHCO)2O]是无色油状液体，吸湿性很强；催剂一浸取一过滤一深度除锰深度除铜一过滤一操作日一操作日一电解一2废锌③四乙酸硅是米黄色晶体，可溶于苯，遇水会迅速水解，超过160℃时可分解成乙滤渣】滤渣2水溶液有机相酸酐和二氧化硅；已知：①“浸取”时，ZnO、CuO转化为[Zn(NH3)4]2+、[Cu(NH3)4]2+进人溶液；④乙酰氯(CH.COCI)是无色油状液体，遇水剧烈反应②25℃时，Kp(CuS)=6.4×10-36,Kp(ZnS)=1.6×10-24;回答下列问题：,其侧边导管的作用是n(杂质离子)(1)仪器1的名称是③深度除杂标准：溶液中N<2.0X10(2)干燥管中碱石灰的作用是(1)“浸取”温度为30℃时，锌的浸出率可达90.6%，继续升温浸出率反而下降，其(3)取255 g SiCL4放人1L的仪器2中，关闭旋塞3，再用仪器1滴入稍过量的乙线原因为酸酐，发生反应，放出大量的热，混合物略微带色，反应一段时间后仪器2底部(2)实验室进行过滤操作时需要用到的玻璃仪器有,操作a的名称是有大颗粒晶体析出。写出制备四乙酸硅的化学方程式：,该过程中，产生的固体杂质是(填化学式)，玻璃管5的管口(3)“深度除锰”是将残留的Mn+转化为MnO2的过程，离子方程式为必须保持在液面上方的原因是」(4)待放置一段时间，用干冰一丙酮冷冻剂冷却，然后】(填具体操(4)“深度除铜”时，锌的最终回收率、除铜效果[除铜效果用反应后溶液中的铜锌比作)，小心缓慢地除去仪器2中残留的液体，接着再分两次用仪器1各滴入75mL左右的乙酸酐，再缓慢除去，若四乙酸硅的产率为84.6%，则得到精制四n(Cu2+)n([Zn(NH,),表示]与0N1).S加人量用整器×19表不的乙酸硅的质量为g。18.(13分)氮及其化合物在科研及生产中均有着重要的应用。根据所学知识回答下关系曲线如图所示。列问题：【23·(新高考)ZX·MNW·化学·HUB】⊙化学卷（九）第6页（共8页）【23·(新高考)ZN·MN·化学·HUB】⊙化学卷（九）第5页（共8页）

12等，由反应①②③并根据元素守恒可知，反应①中生成了等量的CI和HCl,但HCIO会电离，I9万0中生成的cC)n=cG0)士aHCO》.而a波中a的cG)二cC)n-cG】a)(注：NaC1电离产生的Na*、CI的浓度相等)，所以c(CI)+c(Cl)=c(CIO)十c(HC1O)+c(Na+),B项正确；由图可知在HCI(aq)中，随着c(CI)增大，c(Cl2)增大，即反应=cC0）K,HCO,则K,（HC0O》减小，nCO①正向移动，c(H)增大，而CIOHCIO)c),cH'n(HCIO)减小，C项正确；由图可知在HCl溶液中，随着c(CI)增大，c(C2)增大，而在NaCl(aq)中，随着c(C1)增大，而c(C2)减小，则C1对C2的溶解可能起抑制作用也可能起促进作用，D项错误。15.(1)恒压滴液漏斗(1分)：正四面体形(2分)(2)吸收水蒸气和酸性气体（写成CO2也给分）(2分)(3)SiCL,+4(CH3CO)2O-Si(CH COO)4+4CH3COCI(2分)；SiO2(1分)：防止结晶析出的四乙酸硅堵塞玻璃管5的导气管口(2分)⊙化学卷参考答案（九）第3页（共6页）【23新教材老高考·ZX·MN·化学】全国100所名校最新高考模拟示范卷公(4)将玻璃管5的管口插入到液体中（或插入到烧瓶底部），再慢慢打开旋塞(2分)；335(2分)【命题意图】本题考查化学实验【解题分析】(3)制备四乙酸硅时，采用SiCl、(CHCO)2O为原料，二者发生反应，生成Si(CH COO):和CH COCI,化学方程式为SiCl4+4(CHCO)2O一Si(CH COO)4+4 CH COC1,因为Si(CH;COO),为米黄色晶体，易堵塞导管，所以该过程中，玻璃管5的管口必须保持在液面上方。(4)为确保三颈烧瓶内呈无水状态，可将三颈烧瓶内的液体抽出。即将玻璃管5的管口插入到液体中（或插入到烧瓶底部），再慢慢打开旋塞，小心缓慢地除去仪器2中残留的液体。理论上255g四乙酸硅的产量m[siCH,C00,]=70golX264g·molX84.6%≈35g。16.(1)[Ar]3d04s2(2分)》(2)烧杯、漏斗、玻璃棒(1分)；分液(2分)(3)Mn++2NH3·HO+H2O2一MnO2↓+2NH+2HO(或其他合理答案)(2分)(4)①过量的(NH)2S能与[Zn(NH3)4]+发生反应[Zn(NH3)4]+十S2-一ZnSY+14NH,↑，且该反应的衡常数K三K。·K(ZS2.16X10“>10,从而导致锌的最终回收率下降(3分)②当(NH)2S的加入量为120%时，铜锌比为2.0×10-6，达到了深度除铜标准，若继续加大(NH)2S的加入量会导致锌的回收率下降且不经济(2分)》(5)2H++2eH2个(2分)【命题意图】本题考查锌的制备工艺分析，【解题分析】浸取”时，ZnO、CuO转化为[Zn(NH3)4]+、[Cu(NH3)4]+进入溶液，氯化铵溶液呈酸性，与FezO3、MnO反应生成Fe3+、Mn2+,Fe3+、Mn+在氨水中形成Fe(OH)3、Mn(OH)2沉淀，SiO2难溶于水，“滤渣1”的成分为Fe(OH)3、Mn(OH)2和SiO2,加入过氧化氢“深度除锰”，反应的离子方程式为Mn++2NH3·H2O+H2O2MnO2+2NH+2H2O,加入(NH1)2S除铜，“滤渣2”为MnO2、CuS。(1)“浸取”温度为30℃时，锌的浸出率可达90.6%，继续升温浸出率反而下降的原因为温度过高，氨的挥发量增加且NH,C1会分解，生成的[Z(NH),]+减少，不利于废锌催化剂中锌的浸出。(3)“深度除锰”可将残留的Mn+转化为MnO2,Mn元素化合价升高，被氧化，H2O2作氧化剂，O元素化合价降低，该反应的离子方程式为Mn2+十2NH3·H2O+HO2MnO2￥+2NH +2H2O.(4)①当(NH)zS的加入量>100%时，锌离子和硫离子结合生成ZS沉淀，锌的回收率下降的可能原因是过量的(NH)2S能与[Zn(NH3)4]2+发生反应[Zn(NH3):]++S-一ZnS￥+4NH,◆，且该反应的衡常数K=K。·K,（2S一2.16X10“>10,导致锌的最终回收率下降。n(Cu2+)@“深度除铜”时，溶液中乙C,≤2.0X10,由图像可知，当NH,)S的加入量为120%时，铜锌比为2.0×106，达到深度除铜标准，若继续加大(NH),S的加入量会导致锌的回收率下降且不经济。(5)“电解”时，使用惰性电极，阴极是阳离子得电子发生还原反应，溶液中存在H、Z+,氢离子的得电子能力比锌离子强，则竞争反应的电极反应式为2H+十2©一H2个17.(1)①N2(g)+O2(g)=2NO(g)△H=+181.5k·mol1(2分)⊙化学卷参考答案（九）第4页（共6页）【23新教材老高考·ZX·MN·化学】全国100所名校最新高考横拟示范卷入②选择性(1分)③AD(1分)(2)不能(1分)：<(2分)(3)①384(2分)②不变(2分)

L enhs0n Douyne Chneseof thevidingTikTok,and many have tuedntL moved by the hospitality)fkof thepeople in Wuhan,and said they are always helpful and supportive.ficom the ocagovemofWuhan fis hmtopromothe carryingo of preferential (policies.Liu opened his second branc the end of ast year.He plans to expand morewhen the opportuntyisHe said his decisionouruiserepreeriadream inWuhan was right.Wuhan isa city with huge consumtion potential,nice peope and supportive goverment,s Liuwould choose Wuhan again if he had to do it over.24.Where did Liu Tzu-wei first launch his business?A.In Wuhan.B.In Taiwan.C.In London.D.In Hangzhou.25.How would Liu feel about the future of his milk tea shop?A.It's unexpected.B.It's hopeful.C.It's challenging.D.It's regretful.26.What can we learn from the passage?A.All the fans have turned into customers.B.Liu's business was an instant hit in Wuhan.C.Liu worked as an e-shopping agent after graduation.D.Liu's business has received assistance from the government.27.What message does the story convey?A.Well begun is half done.B.East or west,home is best.C.Victory belongs to the most persevering.D.He that travels far knows much.CTake the wheel of an electric vehicle and prepare to be amazed.The latest technology is there,withtablet like screens instead of old-fashioned switches.Add falling price which make owning and runningmany electric vehicles as cheap as fossil-fuel alternatives,and the open road signals.Above all,the instantacceleration of battery power makes driving easy and exciting.EV should be recharged roughly every 250 miles.When you do find a public charging point,it issometimes inaccessible,which cause "range anxiety It is one of the main reasons drivers give for notbuying an EV.Who might install them?Drivers will need a mix of fast"long distance"chargers installednear motorways and ower"tpup"chargers available in the car parks of shopping centers,restaurantsand so on.Dedicated charging firms and carmakers are investing in infrastructure )Oil com-panies are putting chargers in petrol stations and buying charging companies.Yet the charging busines suer from big problems.showtoadjust between the planning auhorities and grid(ms.Another is the osTstthPos may bediffcu t ttain becausethe etrkswill ot at st be heaviyusd.reatediskthat the coveewill have gaps.nd thethereistheu of cmetingrvshoulbe ble wthomherwithout having to sign up to them all.What todo?GovesA well a fnding EV mayare thrwing h atpublic harger mericad50i by.B pstorequirewulheethe problem of cvnve will remain.28.Which is the biggest highlight of an EV?A.Falling price.B.Replacing switchesC.Running self-drive.D.Instant acceleration of battery power.29.What do the underined wordsange anxiety"n Paragraph 2 refer to?Y高三模拟卷（八）：英语·A区专用，第4页（共八页）】

BreakBackspace新课程高三第40期总19081期2022年4月5日星期二ey国内统-刊号CN14-0702/(F)网址http:/ww.xyybs..com配套教学PPT)六)分150分)听第9段材料，回答第14至17题。14.What is the probable relationship betweenthe two speakers?A.Couples.B.Colleagues.C.Neighbors15.Why did the man miss watching the movie?A.He fell sick.B.His eyes hurt.C.He had a sleep.6.What type of show does the public never gettired of?A.Game showsB.Talk shows.C.Situation comedies.7.Which channel is the sitcom on?A.Channel 5.B.Channel 9.C.Channel 11.听第10段材料，回答第18至20题。What do people with FOMO worry about?A.Living a busy life.BMissing out on happy things.

33.What is the author's purpose of writing paragraph 2?A.To describe how whales hunt for food.B.To introduce the living habits of whales.C.To analyze why whales are affected by ship noise.D.To explain how whales benefit from the drop in noise.34.What can be Michael's attitude towards the living condition of fish and whales?A.Annoyed.B.Concerned.C.Puzzled.D.Surprised.35.What are the last three paragraphs mainly about?A.Standards of docking feesB.Measures to reduce ocean noiseC.Concern for the increase in noise.D.Future adjustments about pilot programs.第二节（共5小题：每小题2分，满分10分）根据短文内容，从短文后的选项中选出能填入空白处的最佳选项。选项中有两项为多余选项。Being friends with people with dementia()benefits you bothAs the New Year approaches,many people get together with their friends,raise theirglasses,and sing Auld Lang Syne.They ask,"Should old acquaintance()be forgotten,andnever brought to mind ?The answer is obviously "no".What should we do?36However,for manyolder people who have friends with dementia,they may have different responses to the question.And recently,a research has suggested that social interaction is beneficial to people withdementia as well as their friends.Friendship is important for people with dementia.37Besides,some olderpeople with dementia have no family members to take care of them.How friends react can be amatter of life and death for them.38 They may gain knowledge and experience in the interaction with people withdementia.Condition of people with dementia varies a lot and there's no fixed instruction for aninteraction.That means the way people talk to someone with the disease largely depends ontheir experience.39Although medicine now has no cure to offer,it does not mean there is nothing we can do.We ought to do what we can to make life better for older adults.40A line in AuldLang Syne,"we'll take a cup of kindness yet,for auld lang syne",gives us the answer.A.We should keep our friendship as time goes byB.They are part of our community and need our kindness.C.But how can we improve the lives of older people with dementia?

W:Do you want to watch a movie tonight?I have a lot of new ones.M:I have to do my homework and then eat dinner with my family.But I can come over after that.W:Great.I have all the recent ones.I just got the new Star Wars movie.We could also watch Frozen II or NeZha.M:Oh,I really wanted to see Ne Zha.It is still hard to find,though.How did you find these new moviesalready?W:I downloaded them for free.M:You shouldn't do that.Filmmakers work very hard on making these movies.Unless we buy them or seethem in theaters,the movie industry can't continue to exist.We need to support the filmmakers.听下面一段对话，回答第14至第16三个小题。现在，你有15秒钟的时间阅读这三个小题。(Text 9)W:Good morning,Beautiful Smile Dentistry!How may I help you?M:Good morning,I'd like to schedule a check-up.W:I'd be happy to do that for you.Have you been to Beautiful Smile before?M:Yes,I have.My last check-up was six months ago.W:Great!Can I get your name,please?M:Of course.My name is Steve Cook.W:Thank you,Mr.Cook.Which dentist did you see on your last check-up?M:I'm not sure,really.I'm a bit forgetful.W:That's OK.Let me check your chart.Oh,it's Dr.Lee.He has time next Thursday morning.Is that OK?M:Hmm,that's not good.I've got to work.How about the next day?W:OK.Would you like to suggest a time?M:Does he have anything open in the afternoon?W:Yes.We could fit you in at 2:30 in the afternoon.M:Great.That'll work.W:OK.Thank you for calling,Mr.Cook!We'll see you next week.M:Thank you！Bye-bye！听下面一段独白，回答第17至第20四个小题。现在，你有20秒钟的时间阅读这四个小题。(Text 10)W:Welcome to the introduction to the London Tea Trade centre.Now,look at this picture.It's the Lon-don Tea Trade Centre.As you can see,it is on the north bank of the River Thames.It is the center of animportant industry in the everyday life of the British people.Tea is the British national drink.Every man,woman and child over ten years of age,has an average over four cups a day,or some one thousand five hundredcups annually.About 30 percent of the world's export of tea makes its way to London.And Britain is by far thelargest importer of tea in the world.Now in the second picture,you can see how tea is tasted in the Tea Trade Centre before it is sold.Here,different types of tea are tasted by skilled teatasters before they are sold at each week's tea sale.It's amazing tosee them at work!Over a hundred kinds of tea are laid out in a line on a long table.The tasters generally tastetea with milk,since that is how the majority of British people drink their tea.The tasters move down the linewith surprising speed,tasting from a spoon and deciding what is a fair price for each tea.第二节到此结束。现在，你有两分钟的时间将试卷上的答案转涂到答题卡上。听力部分到此结束。【高一英语·参考答案第3页（共4页）】·22-12-283A·

WRITINGOne possible version:September 23 FridaySunnyIII.1.beautiful2.were made 3.truthI was excited to have my first dough figure4.visited5.interesting 6.actuallyclass today.We learnt about the materials and7.himself8.products9.to avoidtools first.To make dough figures,dough,food10.morecolorings,and scissors are needed.Then theteacher taught us how to make a dough tiger.Itwas a little difficult,but I had great fun in thewhole making process.Section B同步练1.completed2.lively3.liveliest岩养淫报社4.completely5.readingEARNINGENGLISH能力提升基础训练九年级山西第5期I.1.its2.forms3.scissors能力提升4.balloons5.international(Unit 5)情景反应1-5 BABCCII.1.paper cutting2.are sent out听力部分.A3.turned into4.slowly rose into5.at a high heatIII.1.ask for help 2.other celebrations3.bamboo4.good wishes5.red paper6.flowers7.new year8.very real9.fire10.life and beautygASelf Check听力材料基础训练A.1.ago2.in3.to01 M:What was the old man doing when you saw4.were5.to6.buthim?7.each8.than9.whatW:He was sleeping on the grass.10.themB.1.began2.more important3.memories4.was taught2 M:What kind of books would you like to choose?5.their6.differentW:Well,I'd like to buy a fairy book for my little7.carefully8.to makesister.9.performance10.traditional®3 W:How is the weather today?M:It is a little cold.You'd better wear gloves第4版READINGwhen you ride to school.4 M:I plan to go on a trip to Japan next month任务型阅读Have you ever been there?W:Not yet,but I heard that it is a clean and1-5 EFCADbeautiful country.5 M:There is a book fair in the park.Would youlike to go with me tomorrow?W:Sure.I want to buy some novels there.

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ENGLISH(上接第14版中缝)Well,plaviolf used to be myEARNINGfavorite hobbyBut now I spend学关诉thestENGLISHhebyPdre55ea9(上接第2版)Have you got any other hobbies?ant comprehension questions.M:Um.I guess I enjoy playing.ts'screens at once and gaugemlnecopueganetee第二节（共5小题；每小题2.5分，满分12.5erehplynheadditional support.They alsoames and me make new阅读下面短文，从短文后的选项中选项。选项中有两项为多余选项。lessonsfriend Hoy youend muchochildren reach proficiency inW:Well,I'm not interested in computerAcademic conferences are an essential partat I am doing can really makegames.I think there's no sensein spending time playingattending academic conferences is helpfulth it.somethingsrar()with the opportunity to listen to different pohe closure?eerch eto face withmy friends.more great people.There are countless bM:Ilike chrndsconferences.W:Oh,itm cassouEnglish teacher is cominAfter37 If you want to know about thehe closure.class inoue you to someof my friends.(17)before they are even published in journaleading ability.Text 10dents improve their readingHello veryone and welcome toto be.Many researchers will present finour company.My name is Jamespublished at a conference.Brown and Iwork in the HRYour journey to a new place for a coown problems.department.I'm the informationofficer.(18)Now,I'd like to giveher students'needs.you a short introduction to my jobnew place,you may eat new food,visit loxercises more interesting.and also to explain the programfor the day.I'm in charge of alla new language and make some good frieg tests before each class.communications.And I'm also your39 Giving a talk or presentatioParagraph 4 probably mean?guide for the day,so please ask meif you have any questions.As youin front of an audience.And you'll learnControl.D.Change.can see from the program,wehave a tour of the production areascribe the author?with Kim Taylor,our productionResponsible and flexible.manager,then lunch at 12:30.(19)After lunch we have a video to showHumorous and considerate.you at 2:00,then a meeting with John第一节（共15小题；每小题1分，满影White,our marketing manager.Forthis evening we have booked dinnerat 8:00 at the Six Seven,a wonderful阅读下面短文，从每题所给的Arestaurant in the town center.We'llcollection and say,'Oh,thesemeet at your hotel at 7:15 and walk人空白处的最佳选项。Wallace says."The artists putthere.(20)Right,that's all I want tosay.Does anyone have any questions?The tech industry created manyfor the price that they shouldOK,thank you for listening.NowI'm going to hand it over to Kim.So.how they are used by kids,they usuallyhave a good day!My kids 42 iPhones very earlyrecently?本期参考答案husband and I 43 after we got new本期第1-4版1-5AABCB6-10 CBACBlearned the English words on her ow11-15 ABABB16-20 CABCA21-25 BCADB26-30ABBCBwas 44 by simple apps that couldr31-35 DDACDly show?41-45 CBDAC36-40 FAGCDchildren's stories to her.At that time,51-55 BACBD46-50 DABDC57.listed56.whichusually permit her to use iPhone as aerson.59.living58.has droppedThings were good for a few yeaworld.G60.earlier61.undoubtedly62.ins a traditional art piece.63.awas 47 the first time I caught her w65.volunteers64.to enrich

34.What can we learn from the passage?第二节阅读短文，根据语篇要求填空，使短文通顺、意思A.The documentary Top Land is more popular than On完整。每空限填一词。the Road.四A mouse saw a bucket (of corn.There was a small hole in the阅B.The couple went to the Amazon rainforest to avoidbucket.The mouse was hungry,so he got into the bucket through the holeCOVID-19.and ate much cornC.The couple seldom attended international meetings onBut he failed ta6 leave the bucket because his belly (waseducationIt wasn't the first time that they had visited the Amazontoo big.The mouse started crying.A rabbit passed by and asked why.The理解mouse said,"I got into the bucket through the hole.Now I can't go outrainforest.35.What's the purpose of the passage?填because my belly is big”“Wait your belly becomes smal,”said theA.To explain why the Chinese couple took the trip.rabbit and then she left.The mouse fell asleep in the bucket.The next morning.his bellyB.To advise people to take a round-the-world trip.was small.But he was hungry again.He forgot everything and ate moreTo introduce the couple and the documentary Topcorn.Ag a result,he couldn't leave the bucket again.At that moment,Land.D.To look for people who want to take a trip with the_cat found the mouse and ate him.When the rabbit learned aboutthat,she shook her head and said,“Greed(贪婪)is the cause of manycouple.nisfortunes(不幸).”A:Hi,Joe.I love your photos of polar bears.(71)The word comes from Greek with"phil'meaning"a lover of and"math"meaningWhere did you take themHumans are all philomaths to some degree..We want to understand五B:I took them in the Arctic(北极地区)A:Wow that's amazing When did you go there?阅the world Our brains give us the ability to learn throughout our livesThough many people love learning.there are plenty who can't standB:(72)I went there three years agoMy father took meit.Lots of people remember their school days as being boring or even补there arwe stayed there for about half a month.It was really excitingpointless.Scientists have suggested that if an idea is boring,itA:(73)Why do you like the Arctic so much驛becomes harder to connect old ideas with new ideas together.ThisB:I like the Arctic because I think it's the cleanest place in the world.Andnegative(消极的)experience of education at school may lead to peopleavoiding learning opportunities in later life.So.don't let a bad educational experience prevent you learning something对Aouyou oen see polar bears thereB:Yes,we could.Polar bears are the most active between March and Maynew.Evolution(进化)hasmmC(内s的)phitomath.4长elong eamers and try to discoveroWe went there in April and could often see themA.Why is this?A:Sounds great.I wish I could go there one day.B We're interested in eveB:I plan to start my next journey to the Arctic with my father next yearC.Who knows whatwe can achieve?Would vou like to ioin us?D.It means a person who loves to study.A:(75)Yes,I'd like toI need to makeE.Therefore,we will lose interest and get less informationpreparations nowhson was on the vway.Kelly couldn't 41 to race on the假如你是王丽，你的英国笔友Toy最近在交友方面遇三六到一些困惑。不久前，他发来邮件向你寻求帮助。请你给他回一封邮件。词数不少于100（开头和结尾已给出，不计入总词数)。完形填空aDear Wang Li,面have a good friend at school.He is active.And he is friendly and helpfuI knowy that'sto everyone.I'm proud of being friends with him.However,my parents51said "Rut it sounde likews for vour teamKelly thedon't allow me to play with him because he isn't good at study.They askd being the fastessheared moreabout theme to make friends with"good kids".In their eyes,"good kids"are thoseked them to play a gangot the ball and53passed it to Kelly.Then Kelly kieked it hard towardsstudents with high scores.This troubles me deeply.Should I listen to themhecan beYours,Thankswe pullgTonyre rightthaSesaidC41.A.agreeB.expectC.waitD.standD 42.A.usB.herC.himD.themC43.A.coachB.managerC.runnerD.leaderDear Tony,B44.A.busyB.silent.awakeD.healthy六I'm sorry to hear that you have trouble.I'm glad to helpA 45.A.alwaysB hardlvC.sometimesD.neveryou.B46.A.callB.beatC.inviteD.believeB47.A.tiredB.nervousC.happyD.surprisedD 48.A.talk back toB.look back atC.keep away fromD.catch up with面D49.A.disappearedB.attendedC.competedD.laughedC 50.A.imagineB.discoverC.explainD.predictA 51.A.disappointingB.meaninglessC.interestingD.understandingI hope everything will go well with you soon.B.52.A.ballB.teamC.gameD.practiceYours,A53.A.quicklyB.widelyC.luckilyD.clearlyWang LiC.54.A.checkedB.sharedC.scoredD.reportedD.55.A.unlessgB.althoughC.untilD.ifexceawful写作指导：四boy named第一节六本篇作要求同学们写一封邮件，写作重点是解答Before the Christmas holiday I reaa story The Litlest Angel to theToy的困惑，并为他提出一些合理的建议。阅读短文，从class.This ltle angel had in heaven.He语篇©主题：人与社会之社会服务与人际沟通方框中选择适his happy time i⊙子主题：良好的人际关系与社会交往当的词并用其the past.show-and-tell time the next day,David sat in front of©主要时态：一般现在时回主要人称：第一人称正确形式填空，the class with a box."This is my first tooth,"he explained."This is.."He⊙行文布局：空使短文通顺、afraiwhen go表意思完整。每take so that I can always remember you"Knowing th box①分析原因I think your parents do that because they want you to空限填一词，or te dayeparnice and ten pcedget higher scores in tests by making friends with the topWhen the holiday was over.all the students returned to school每词限用一次。except He上students.I have neveremember the"little angel".and his box full of love forever.3

听第7段材料，回答第8至10题。8.What is the woman doing?A.Teaching the baking skills.B.Giving opinions.C.Picking cookies..What oes the womn probably think of the ch cke?A.It's too sweet.B.It's very soft.10.What do we know about the last cookie?C.It's very dryA.The speakers made it.B.The man bought it from a store.余黑。如需改C.The woman got it as a Christmas gift.写在本试卷上听第8段材料，回答第11至13题。11.What is the probable relationship between the speakers?A.Brother and sister.B.Shop owner and customer.C.Former neighbors.12.What has been built in place of the video store?答案转涂到A.A parking lot.B.A cinema.13.Who did the speakers saw in the end?C.A shopping mall.A.A video store owner.B.Mr.Otto.最佳选项。听第9段材料，回答第14至17题。C.The theater manager遍。14.How did the man plan to go to werk today?A.By bike.(B.On foot.C.By car.15.How long was the man late?A.30 minutes.B.45 minutes.C.75 minutes.16.Why was the man extra late?v.bA.He started out lateB.He walked very slowly.C.He was waiting a long time for help17.What does the woman plan to do?A.Ask the man's mother for advice.B.Get the other group members to come laterC.Tell the man the meeting time much earlier next time.听第10段材料，回答第18至20题。18.Why should the dirt be loose?A.To fill the pot more.B.To let the seed spread.选C.To let more sun inHawa53-boo od n19.How does the speaker measure the water?A.By checking the pot.B.By using her fingerC.By counting up.20.What is the talk about?oA.Protecting a tree.B.Growing a plant.C.Finding some apples.【2023高考名校导航冲刺金卷·英语（一）第2页（共8页）】

39.F。根据本空前的You can edit your video.To learn how to edit,I just took online courseson how to use particular editing programs及本空后的Use attractive titles and create a colourfulthumbnail for your video可知，本空内容应与“编辑视频”相关，且在文中起承上启下的作用，F项符合语境。F项中的Once you've edited your video承接本空前的内容，it's all aboutgetting it seen by people呼应本空后的attractive titles和a colourful thumbnail。40.D。根据本空前的every YouTuber will receive a negative or unpleasant comment.Pleaseremember,this is not a reflection of your hard work及本空后的Ignore the negativity and justfocus on the positive comments you receive可知，本空内容应讲述不要因为负面的评论就质疑你的视频，故D项符合语境。语言知识运用第一节主题语境：人与自我一一做人与做事本文是记叙文。文章讲述了护士Jennifer Smith帮助一名空巢老年患者照顾他的宠物狗的故事。41.C。根据文章首句中的an early morning phone call及下文中的‘Boomer is in an animalshelter!'和Iwill.Boomer and take care of him for you可知，Burley很担心他的宠物狗Boomer。42.A。文章首句It was right after Thanksgiving that nurse Jennifer Smith got an early morningphone call from John Burley,one of her patients提示本空选择calling。43.D。根据上文中Burley一大早给Smith打电话的行为及下文中的The60-year-old lived.with Boomer可知，小狗Boomer对主人Burley来说非常重要，world符合语境。44.A。下文中的Iwil.Boomer and take care of him for you及so when he was hospitalized forlung problems,,he had no one to take care of his dog说明Burley想让护士Smith帮他照顾宠物狗，故选take care of。45.C。根据本句中的take care of him for you及下文中Smith寻找小狗Boomer的行为可知，Smith答应Burley自己会找到Boomer,并照顾它。46.A。根据下文中的Most of his family lives in Arkansas,so when he was hospitalized for lungproblems,he had no one to take care of his dog可知，60岁的Burley和宠物狗Boomer独自生活在一起，故选alone。47.D。根据上文中Burley给Smith打电话请求她帮忙照顾小狗的行为及Most of his familylives in Arkansas,so when he was hospitalized for lung problems,he had no one to take care ofhis dog可知，只有Smith可以帮助Burley照顾Boomer,except符合语境。48.c。根据上文的描述可知，小狗Boomer对主人Burley来说很重要。结合本句中的showingoff pictures of his dog可知，Burley经常谈论自己的小狗Boomer,talk about符合语境49.B。根据上文的描述及下文中Smith寻找小狗Boomer的行为和Right now the focus is onBurley getting.and taking Boomer home one day可知，Smith会帮助Burley照顾小狗，等他身体康复后，将它还给他。也就是说，她不会让他们分开的。50.B。上文中的‘Boomer is in an animal shelter!'和下文中的nearby animal shelters提示本空选择shelter。5l.D。本段描述Smith寻找Boomer的过程。根据上文中的Burley didn't know which.Boomerwas in及下文中的she called the Rome Humane Society可知，Smith查询了附近的动物收容所。设空处所填的词应该与“查询”具有相同或相近的含义，故选looked up。52.A。根据上文的描述可知，Smith乐意帮助Burley照顾小狗。结合下文中的She took an earlylunch the next day and drove to the shelter可知，Smith打听到Boomer的下落时感到很高兴。设空处所填的词应该与“高兴”具有相同或相近的含义，故选happy。

Human historyHuman history at Biscayne begins more than 10,000 years ago.Scientists say evidence of the area's earliestpeople is mostly underwater now and learn about these people by examining the hills of shells they left behind.Asthe population grew,it divided into separate cultures.The groups began making pottery and created trade networks.These Native Americans are called the Tequesta.The Tequesta depended on the rich food source of the sea tosurvive.They were not centered on farming and had more time than other natives for art and religion.The reefs andrough waters made it difficult for early explorers resulting in more than 50 shipwrecks.Scuba divers today canexplore six of them.Exploring the parkMany visitors to Biscayne National Park choose to explore underwater.Guides lead snorkeling and scubadiving trips.At Boca Chita Key,visitors can explore a lighthouse,a symbol of Biscayne National Park built in the1930s.But visitors to Biscayne National Park probably are not there to see skyscrapers and city lights.The beautyin Biscayne is quiet waters,rustling mangroves.21.What is the feature of the ecosystem in the Biscayne National Park?A.The mixed biological communities.B.The different species of the animals.C.The low-lying islands or reefs.D.The clear and warm waters.22.What can we know from the last two paragraphs?A.Human history dates back to more than 50,000 years ago.B.The Native Americans prefer farming to fishing.C.Scuba divers today are to see skyscrapers and city lights.D.Biscayne is a paradise for the water sports enthusiasts.23.Where is the text most probably taken from?A.A personal diary.B.A travel magazine.C.A geography textbook.D.A book review.心As a reporter,I talk to strangers for a living and love the challenge of getting them to open up.Yet here's aconfession:I've been married for eight happy years,but until six months ago,I could be the stereotypicalinattentive husband.It's not that my wife and I never had pleasant conversations.But more often than I care to admit,I was justgoing through the motions,nodding when I was supposed to..I was the guy who'd defensively snap(厉声说)，“Ofcourse I did!"when my wife would ask,"JB,did you even hear what I just said?"In January,I began to lose my voice repeatedly.Doctors told me I needed surgery,or else my throat would bepermanently damaged.Total silence would be required for the first few weeks of my recovery.Two hours after the surgery,my eyes filled with tears as my two-year-old son stood by me looking puzzledbecause I wouldn't answer his questions.I wanted to talk but couldn't.But before I got home,I had settled into a Zen-like peace about my silence.Soon I noticed another "sideeffect":As my wife talked to me to keep up my spirits,I wasn't just hearing her;I was listening to her.Over the next few weeks,I found myself unwilling to miss a word she said.I began to hear a sweetness in hervoice that I hadn't recalled for long.I found myself understanding her better on topics I'd previously dismissed as“things I just don't get as a guy.”I also realized my toddler(学步的儿童)wasn't just chattering nonstop but that he often had surprisinglythoughtful things to say for his age.Even while walking my dog in the woods near our home,I began hearing pleasant patterns in bird songs.The英语试题第3页（共8页）

1.①n.东道主②v.主办2.①v.出汗②n.汗水3.①v.作弊②n.骗子PART 2I.1.build up my strength2.bringing honour to China3.set a good example4.the master of the football fieldⅡ.1.champion2.injured3.give up4.lose heart5.athletes6.failure(s)PART 3I.1.Compared with to weight lifting2.make a difference3.rather than4.cut out high-fat foodsⅡ.1.isn'the2.No,I didn't3.doesn't it4.isn't it5.Yes,it was;isn't it语言知识应用篇1.a 2.to try3.addicted4.with 5.which 6.has provided

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1、2023全国一百所名校最新高考冲刺卷高考样卷语文

1、2023全国一百所名校最新高考冲刺卷高考样卷语文

1.A(曲解文意。由第一段可知。)2.B

1925年12月，在联共（布）第十四次代表大会上通过了苏联社会主义工业化的方针，提出材料二“为苏联社会主义建设胜利而奋斗是我们党的基本任务”的社会主义工业化发展战略。在特史条件下，苏联共产觉人进择了高速度优先发展重工业的工业化道路。为了高速度地优先重工业，苏联建立起了高度聚中的工业理体划、计划管理休制、于部管理制度，等等。话后来，苏联北工业化经济发展略方针片面化、国定化、模式化，没有根据变化发展了的普与条件及时做出调整。苏联在工业化过程中，财力和物力都是不充裕的，但依靠党的壁强碎，通过计划管理，较好地调动了广大劳动群众的生产积极性。用十几年的时间，跑完了西先进资本主义国家100年才走完的路程。一摘编自汤德森《苏联国家工业化的伟大实践及其经验教训》()根据材料一并结合所学知识，概括法国工业化发展道路面临的困境。(6分)(2)根据材料二并结合所学知识，指出苏联工业化发展道路与西方国家的不同之处，简要说明材料中体现出的苏联社会主义现代化建设道路出现的问题带给我们的启示。(8分)阅读材料，完成下列要求。(12分)材料geannette图41924年刊登在上海《大陆报》上的星期特刊一《外侨购物指南》(备注：《大陆报》是美国人在上海创办的第一份在华美式报纸)提取材料中的信息并结合所学知识，自拟论题，阐述自己的历史认识。（要求：主题明确，史论结合，逻辑严谨，表述成文。)